Improved Conditions for the Visible-Light Driven Hydrocarboxylation by Rh(I) and Photoredox Dual Catalysts Based on the Mechanistic Analyses

Improved Conditions for the Visible-Light Driven Hydrocarboxylation by Rh(I) and Photoredox Dual Catalysts Based on the Mechanistic Analyses

The improved catalytic conditions and detailed reaction mechanism of the visible-light driven hydrocarboxylation of alkenes with CO2 by the Rh(I) and photoredox dual catalysts were investigated. The use of the benzimidazoline derivative, BI(OH)H, as a sacrificial electron donor was found to increase...

Full description

Bibliographic Details
Main Authors: Kei Murata, Nobutsugu Numasawa, Katsuya Shimomaki, Jun Takaya, Nobuharu Iwasawa
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-05-01
Series:Frontiers in Chemistry
Subjects:
carboxylation
CO2 fixation
photoredox catalyst
rhodium catalyst
visible light
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00371/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00371/full

Similar Items