Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2019-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-13663-8 |