Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.

Bibliographic Details
Main Authors: Kui Xiao, Yu Zhao, Jun Zhu, Liang Zhao
Format: Article
Language:English
Published: Nature Publishing Group 2019-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-13663-8
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spelling doaj-f565e56009c0456c94b1b24dda7275912021-05-11T11:42:26ZengNature Publishing GroupNature Communications2041-17232019-12-0110111010.1038/s41467-019-13663-8Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliumsKui Xiao0Yu Zhao1Jun Zhu2Liang Zhao3Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua UniversityState Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen UniversityState Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen UniversityKey Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua UniversityHyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.https://doi.org/10.1038/s41467-019-13663-8
collection DOAJ
language English
format Article
sources DOAJ
author Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
spellingShingle Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
Nature Communications
author_facet Kui Xiao
Yu Zhao
Jun Zhu
Liang Zhao
author_sort Kui Xiao
title Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_short Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_full Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_fullStr Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_full_unstemmed Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
title_sort hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-12-01
description Hyperconjugative aromaticity combines the concepts of hyperconjugation and aromaticity and explains cyclopentadiene stability. Here, the authors demonstrate extended hyperconjugative aromaticity in a metallated indole ring, which shows extended electron conjugation due to the dual hyperconjugation.
url https://doi.org/10.1038/s41467-019-13663-8
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AT yuzhao hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
AT junzhu hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
AT liangzhao hyperconjugativearomaticityandprotodeaurationreactivityofpolyauratedindoliums
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