Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data

Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data

The densities of 1,3-butanediol-water mixtures and some tetraalkylammonium iodide salt solutions in these solvent mixtures at different concentrations (0.02 M-0.14 M) have been determined at 298.15 K using magnetic float densitometer technique. Then apparent molar volumes ΦV of the electrolytes in a...

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Main Authors: R. N. Pathak, Indu Saxena, Archna, Anoop Kumar Mishra
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/394108
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spelling doaj-f414fd461eed4616805118bacb1382512020-11-24T23:26:43ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102011-01-01831323132910.1155/2011/394108Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume DataR. N. Pathak0Indu Saxena1Archna2Anoop Kumar Mishra3Department of Chemistry, Lucknow University, Lucknow-226007, IndiaDepartment of Chemistry, Lucknow University, Lucknow-226007, IndiaDepartment of Chemistry, Lucknow University, Lucknow-226007, IndiaDepartment of Chemistry, Lucknow University, Lucknow-226007, IndiaThe densities of 1,3-butanediol-water mixtures and some tetraalkylammonium iodide salt solutions in these solvent mixtures at different concentrations (0.02 M-0.14 M) have been determined at 298.15 K using magnetic float densitometer technique. Then apparent molar volumes ΦV of the electrolytes in above solvent mixtures were calculated. The apparent molar volumes of transfer ∆ΦV° (tr) were also calculated and the ion-ion / ion- solvent interactions are then discussed on the basis of changes in the Masson's slope and apparent molar volumes of transfer data.http://dx.doi.org/10.1155/2011/394108
collection DOAJ
language English
format Article
sources DOAJ
author R. N. Pathak
Indu Saxena
Archna
Anoop Kumar Mishra
spellingShingle R. N. Pathak
Indu Saxena
Archna
Anoop Kumar Mishra
Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
E-Journal of Chemistry
author_facet R. N. Pathak
Indu Saxena
Archna
Anoop Kumar Mishra
author_sort R. N. Pathak
title Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
title_short Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
title_full Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
title_fullStr Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
title_full_unstemmed Study of the Influence of Alkyl Chain Cation-Solvent Interactions on Water Structure in 1,3-Butanediol-Water Mixture by Apparent Molar Volume Data
title_sort study of the influence of alkyl chain cation-solvent interactions on water structure in 1,3-butanediol-water mixture by apparent molar volume data
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2011-01-01
description The densities of 1,3-butanediol-water mixtures and some tetraalkylammonium iodide salt solutions in these solvent mixtures at different concentrations (0.02 M-0.14 M) have been determined at 298.15 K using magnetic float densitometer technique. Then apparent molar volumes ΦV of the electrolytes in above solvent mixtures were calculated. The apparent molar volumes of transfer ∆ΦV° (tr) were also calculated and the ion-ion / ion- solvent interactions are then discussed on the basis of changes in the Masson's slope and apparent molar volumes of transfer data.
url http://dx.doi.org/10.1155/2011/394108
work_keys_str_mv AT rnpathak studyoftheinfluenceofalkylchaincationsolventinteractionsonwaterstructurein13butanediolwatermixturebyapparentmolarvolumedata
AT indusaxena studyoftheinfluenceofalkylchaincationsolventinteractionsonwaterstructurein13butanediolwatermixturebyapparentmolarvolumedata
AT archna studyoftheinfluenceofalkylchaincationsolventinteractionsonwaterstructurein13butanediolwatermixturebyapparentmolarvolumedata
AT anoopkumarmishra studyoftheinfluenceofalkylchaincationsolventinteractionsonwaterstructurein13butanediolwatermixturebyapparentmolarvolumedata
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