Polymeric potassium triformatocobalt(II)

Polymeric potassium triformatocobalt(II)

In the crystal structure of the title compound, poly[tri-μ-formato-cobalt(II)potassium], [CoK(CHO2)3]n the Co2+ cations are coordinated by six O-bonded formate anions in an octahedral coordination mode and the K+ cations are eightfold coordinated by seven O-bonded formate anions within...

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Main Authors: Susanne Wöhlert, Mario Wriedt, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811008737
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spelling doaj-f39b9bd7deb74183ba66e69d379c39082020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m422m42210.1107/S1600536811008737Polymeric potassium triformatocobalt(II)Susanne WöhlertMario WriedtInke JessChristian NätherIn the crystal structure of the title compound, poly[tri-μ-formato-cobalt(II)potassium], [CoK(CHO2)3]n the Co2+ cations are coordinated by six O-bonded formate anions in an octahedral coordination mode and the K+ cations are eightfold coordinated by seven O-bonded formate anions within irregular polyhedra. The Co2+ cations are connected by bridging formate anions into a three-dimensional coordination network in which the K+ cations are embedded. The asymmetric unit consits of one Co2+ cation located on a center of inversion, one K+ cation located on a twofold axis and two crystallographically independent formato anions, of which one is located on a twofold axis and the other occupies a general position. http://scripts.iucr.org/cgi-bin/paper?S1600536811008737
collection DOAJ
language English
format Article
sources DOAJ
author Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
spellingShingle Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
Polymeric potassium triformatocobalt(II)
Acta Crystallographica Section E
author_facet Susanne Wöhlert
Mario Wriedt
Inke Jess
Christian Näther
author_sort Susanne Wöhlert
title Polymeric potassium triformatocobalt(II)
title_short Polymeric potassium triformatocobalt(II)
title_full Polymeric potassium triformatocobalt(II)
title_fullStr Polymeric potassium triformatocobalt(II)
title_full_unstemmed Polymeric potassium triformatocobalt(II)
title_sort polymeric potassium triformatocobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-04-01
description In the crystal structure of the title compound, poly[tri-μ-formato-cobalt(II)potassium], [CoK(CHO2)3]n the Co2+ cations are coordinated by six O-bonded formate anions in an octahedral coordination mode and the K+ cations are eightfold coordinated by seven O-bonded formate anions within irregular polyhedra. The Co2+ cations are connected by bridging formate anions into a three-dimensional coordination network in which the K+ cations are embedded. The asymmetric unit consits of one Co2+ cation located on a center of inversion, one K+ cation located on a twofold axis and two crystallographically independent formato anions, of which one is located on a twofold axis and the other occupies a general position.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811008737
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AT mariowriedt polymericpotassiumtriformatocobaltii
AT inkejess polymericpotassiumtriformatocobaltii
AT christiannamp228ther polymericpotassiumtriformatocobaltii
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