Electrical properties of graphene-metal contacts
Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectro...
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2017-07-01
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doaj-f364cb5bb5f24de48a177b91d043c90c2020-12-08T02:46:31ZengNature Publishing GroupScientific Reports2045-23222017-07-017111110.1038/s41598-017-05069-7Electrical properties of graphene-metal contactsTeresa Cusati0Gianluca Fiori1Amit Gahoi2Vikram Passi3Max C. Lemme4Alessandro Fortunelli5Giuseppe Iannaccone6Dipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16Dipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16University of SiegenUniversity of SiegenUniversity of SiegenCNR-ICCOM, Istituto di Chimica dei Composti OrganometalliciDipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectronic devices. Unfortunately, measurements of contact resistance in the literature do not provide a consistent picture, due to limitations of current graphene technology, and to incomplete understanding of influencing factors. Here we show that the contact resistance is intrinsically dependent on graphene sheet resistance and on the chemistry of the graphene-metal interface. We present a physical model of the contacts based on ab-initio simulations and extensive experiments carried out on a large variety of samples with different graphene-metal contacts. Our model explains the spread in experimental results as due to uncontrolled graphene doping and suggests ways to engineer contact resistance. We also predict an achievable contact resistance of 30 Ω·μm for nickel electrodes, extremely promising for applications.https://doi.org/10.1038/s41598-017-05069-7 |
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DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Teresa Cusati Gianluca Fiori Amit Gahoi Vikram Passi Max C. Lemme Alessandro Fortunelli Giuseppe Iannaccone |
spellingShingle |
Teresa Cusati Gianluca Fiori Amit Gahoi Vikram Passi Max C. Lemme Alessandro Fortunelli Giuseppe Iannaccone Electrical properties of graphene-metal contacts Scientific Reports |
author_facet |
Teresa Cusati Gianluca Fiori Amit Gahoi Vikram Passi Max C. Lemme Alessandro Fortunelli Giuseppe Iannaccone |
author_sort |
Teresa Cusati |
title |
Electrical properties of graphene-metal contacts |
title_short |
Electrical properties of graphene-metal contacts |
title_full |
Electrical properties of graphene-metal contacts |
title_fullStr |
Electrical properties of graphene-metal contacts |
title_full_unstemmed |
Electrical properties of graphene-metal contacts |
title_sort |
electrical properties of graphene-metal contacts |
publisher |
Nature Publishing Group |
series |
Scientific Reports |
issn |
2045-2322 |
publishDate |
2017-07-01 |
description |
Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectronic devices. Unfortunately, measurements of contact resistance in the literature do not provide a consistent picture, due to limitations of current graphene technology, and to incomplete understanding of influencing factors. Here we show that the contact resistance is intrinsically dependent on graphene sheet resistance and on the chemistry of the graphene-metal interface. We present a physical model of the contacts based on ab-initio simulations and extensive experiments carried out on a large variety of samples with different graphene-metal contacts. Our model explains the spread in experimental results as due to uncontrolled graphene doping and suggests ways to engineer contact resistance. We also predict an achievable contact resistance of 30 Ω·μm for nickel electrodes, extremely promising for applications. |
url |
https://doi.org/10.1038/s41598-017-05069-7 |
work_keys_str_mv |
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