Electrical properties of graphene-metal contacts

Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectro...

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Main Authors: Teresa Cusati, Gianluca Fiori, Amit Gahoi, Vikram Passi, Max C. Lemme, Alessandro Fortunelli, Giuseppe Iannaccone
Format: Article
Language:English
Published: Nature Publishing Group 2017-07-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-017-05069-7
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spelling doaj-f364cb5bb5f24de48a177b91d043c90c2020-12-08T02:46:31ZengNature Publishing GroupScientific Reports2045-23222017-07-017111110.1038/s41598-017-05069-7Electrical properties of graphene-metal contactsTeresa Cusati0Gianluca Fiori1Amit Gahoi2Vikram Passi3Max C. Lemme4Alessandro Fortunelli5Giuseppe Iannaccone6Dipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16Dipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16University of SiegenUniversity of SiegenUniversity of SiegenCNR-ICCOM, Istituto di Chimica dei Composti OrganometalliciDipartimento di Ingegneria dell’Informazione, Università di Pisa Via G. Caruso 16Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectronic devices. Unfortunately, measurements of contact resistance in the literature do not provide a consistent picture, due to limitations of current graphene technology, and to incomplete understanding of influencing factors. Here we show that the contact resistance is intrinsically dependent on graphene sheet resistance and on the chemistry of the graphene-metal interface. We present a physical model of the contacts based on ab-initio simulations and extensive experiments carried out on a large variety of samples with different graphene-metal contacts. Our model explains the spread in experimental results as due to uncontrolled graphene doping and suggests ways to engineer contact resistance. We also predict an achievable contact resistance of 30 Ω·μm for nickel electrodes, extremely promising for applications.https://doi.org/10.1038/s41598-017-05069-7
collection DOAJ
language English
format Article
sources DOAJ
author Teresa Cusati
Gianluca Fiori
Amit Gahoi
Vikram Passi
Max C. Lemme
Alessandro Fortunelli
Giuseppe Iannaccone
spellingShingle Teresa Cusati
Gianluca Fiori
Amit Gahoi
Vikram Passi
Max C. Lemme
Alessandro Fortunelli
Giuseppe Iannaccone
Electrical properties of graphene-metal contacts
Scientific Reports
author_facet Teresa Cusati
Gianluca Fiori
Amit Gahoi
Vikram Passi
Max C. Lemme
Alessandro Fortunelli
Giuseppe Iannaccone
author_sort Teresa Cusati
title Electrical properties of graphene-metal contacts
title_short Electrical properties of graphene-metal contacts
title_full Electrical properties of graphene-metal contacts
title_fullStr Electrical properties of graphene-metal contacts
title_full_unstemmed Electrical properties of graphene-metal contacts
title_sort electrical properties of graphene-metal contacts
publisher Nature Publishing Group
series Scientific Reports
issn 2045-2322
publishDate 2017-07-01
description Abstract The performance of devices and systems based on two-dimensional material systems depends critically on the quality of the contacts between 2D material and metal. A low contact resistance is an imperative requirement to consider graphene as a candidate material for electronic and optoelectronic devices. Unfortunately, measurements of contact resistance in the literature do not provide a consistent picture, due to limitations of current graphene technology, and to incomplete understanding of influencing factors. Here we show that the contact resistance is intrinsically dependent on graphene sheet resistance and on the chemistry of the graphene-metal interface. We present a physical model of the contacts based on ab-initio simulations and extensive experiments carried out on a large variety of samples with different graphene-metal contacts. Our model explains the spread in experimental results as due to uncontrolled graphene doping and suggests ways to engineer contact resistance. We also predict an achievable contact resistance of 30 Ω·μm for nickel electrodes, extremely promising for applications.
url https://doi.org/10.1038/s41598-017-05069-7
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