(Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate

(Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate

Single crystals of the title compound, [Co(C6H4NO2)(C18H27N6P)]NO3, were obtained from the reaction of nitrato[tris(2-isopropylimidazol-4-yl)phosphane]cobalt(II) nitrate with picolinic acid in the presence of potassium tert-butoxide as base. The coordination polyhedron around the central CoII ion is...

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Main Authors: Peter C. Kunz, Guido J. Reiss, Markus Börgardts
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812004485
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spelling doaj-f34ab09e43a746f5a9d85425912ee1962020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m265m26610.1107/S1600536812004485(Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitratePeter C. KunzGuido J. ReissMarkus BörgardtsSingle crystals of the title compound, [Co(C6H4NO2)(C18H27N6P)]NO3, were obtained from the reaction of nitrato[tris(2-isopropylimidazol-4-yl)phosphane]cobalt(II) nitrate with picolinic acid in the presence of potassium tert-butoxide as base. The coordination polyhedron around the central CoII ion is about halfway between square-pyramidal and trigonal-bipyramidal geometry. In the structure, the nitrate counter-anion is connected by N—H...O hydrogen bonding to the complex cation. Additionally, the complex cations form one-dimensional chains along [010] by hydrogen bonding of the NH group of an imidazole ring to the picolinate group of a neighbouring complex cation.http://scripts.iucr.org/cgi-bin/paper?S1600536812004485
collection DOAJ
language English
format Article
sources DOAJ
author Peter C. Kunz
Guido J. Reiss
Markus Börgardts
spellingShingle Peter C. Kunz
Guido J. Reiss
Markus Börgardts
(Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
Acta Crystallographica Section E
author_facet Peter C. Kunz
Guido J. Reiss
Markus Börgardts
author_sort Peter C. Kunz
title (Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
title_short (Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
title_full (Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
title_fullStr (Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
title_full_unstemmed (Picolinato-κ2N,O)[tris(2-isopropyl-1H-imidazol-4-yl-κN3)phosphane]cobalt(II) nitrate
title_sort (picolinato-κ2n,o)[tris(2-isopropyl-1h-imidazol-4-yl-κn3)phosphane]cobalt(ii) nitrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description Single crystals of the title compound, [Co(C6H4NO2)(C18H27N6P)]NO3, were obtained from the reaction of nitrato[tris(2-isopropylimidazol-4-yl)phosphane]cobalt(II) nitrate with picolinic acid in the presence of potassium tert-butoxide as base. The coordination polyhedron around the central CoII ion is about halfway between square-pyramidal and trigonal-bipyramidal geometry. In the structure, the nitrate counter-anion is connected by N—H...O hydrogen bonding to the complex cation. Additionally, the complex cations form one-dimensional chains along [010] by hydrogen bonding of the NH group of an imidazole ring to the picolinate group of a neighbouring complex cation.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812004485
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AT guidojreiss picolinatoamp9542notris2isopropyl1himidazol4ylamp954n3phosphanecobaltiinitrate
AT markusbamp246rgardts picolinatoamp9542notris2isopropyl1himidazol4ylamp954n3phosphanecobaltiinitrate
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