Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction

Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction

A three-component oxidative dehydrogenation tandem reaction via the coupling and hydroarylation of benzaldehyde, aniline and phenylacetylene to a quinoline derivate was catalyzed by an iron-containing ionic liquid. The reaction was air mediated and could be performed under neat conditions. The iron(...

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Bibliographic Details
Main Authors: Maren Muntzeck, René Wilhelm
Format: Article
Language:English
Published: MDPI AG 2016-06-01
Series:International Journal of Molecular Sciences
Subjects:
ionic liquid
C–H activation
oxidation
iron
catalysis
hydroarylation
Online Access:http://www.mdpi.com/1422-0067/17/6/860
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spelling doaj-f3331782c90e4bf495eb8e3fda9ea5482020-11-24T21:54:01ZengMDPI AGInternational Journal of Molecular Sciences1422-00672016-06-0117686010.3390/ijms17060860ijms17060860Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem ReactionMaren Muntzeck0René Wilhelm1Department of Chemistry, University of Paderborn, Warburgerstr. 100, Paderborn 33098, GermanyDepartment of Chemistry, University of Paderborn, Warburgerstr. 100, Paderborn 33098, GermanyA three-component oxidative dehydrogenation tandem reaction via the coupling and hydroarylation of benzaldehyde, aniline and phenylacetylene to a quinoline derivate was catalyzed by an iron-containing ionic liquid. The reaction was air mediated and could be performed under neat conditions. The iron(III) of the ionic liquid was the oxidizing species.http://www.mdpi.com/1422-0067/17/6/860ionic liquidC–H activationoxidationironcatalysishydroarylation
collection DOAJ
language English
format Article
sources DOAJ
author Maren Muntzeck
René Wilhelm
spellingShingle Maren Muntzeck
René Wilhelm
Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
International Journal of Molecular Sciences
ionic liquid
C–H activation
oxidation
iron
catalysis
hydroarylation
author_facet Maren Muntzeck
René Wilhelm
author_sort Maren Muntzeck
title Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
title_short Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
title_full Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
title_fullStr Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
title_full_unstemmed Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction
title_sort influence of ionic liquids on an iron(iii) catalyzed three-component coupling/hydroarylation/dehydrogenation tandem reaction
publisher MDPI AG
series International Journal of Molecular Sciences
issn 1422-0067
publishDate 2016-06-01
description A three-component oxidative dehydrogenation tandem reaction via the coupling and hydroarylation of benzaldehyde, aniline and phenylacetylene to a quinoline derivate was catalyzed by an iron-containing ionic liquid. The reaction was air mediated and could be performed under neat conditions. The iron(III) of the ionic liquid was the oxidizing species.
topic ionic liquid
C–H activation
oxidation
iron
catalysis
hydroarylation
url http://www.mdpi.com/1422-0067/17/6/860
work_keys_str_mv AT marenmuntzeck influenceofionicliquidsonanironiiicatalyzedthreecomponentcouplinghydroarylationdehydrogenationtandemreaction
AT renewilhelm influenceofionicliquidsonanironiiicatalyzedthreecomponentcouplinghydroarylationdehydrogenationtandemreaction
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