Tetrakis(benzylamino)phosphonium chloride

Tetrakis(benzylamino)phosphonium chloride

The title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10)...

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Main Authors: Khodayar Gholivand, Hossein Mostaanzadeh, Sedigheh Farshadian
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810054401
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spelling doaj-f29049ba8a87434e8ca86de8275030672020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672o311o31110.1107/S1600536810054401Tetrakis(benzylamino)phosphonium chlorideKhodayar GholivandHossein MostaanzadehSedigheh FarshadianThe title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environments of sp2-hybridized N atoms are essentially planar (sum of angles = 359.9 and 360.1°). In the crystal, the phosphonium ion interacts with each neighboring chloride ion via two approximately equal N—H...Cl interactions, forming parallel chains along the c axis. http://scripts.iucr.org/cgi-bin/paper?S1600536810054401
collection DOAJ
language English
format Article
sources DOAJ
author Khodayar Gholivand
Hossein Mostaanzadeh
Sedigheh Farshadian
spellingShingle Khodayar Gholivand
Hossein Mostaanzadeh
Sedigheh Farshadian
Tetrakis(benzylamino)phosphonium chloride
Acta Crystallographica Section E
author_facet Khodayar Gholivand
Hossein Mostaanzadeh
Sedigheh Farshadian
author_sort Khodayar Gholivand
title Tetrakis(benzylamino)phosphonium chloride
title_short Tetrakis(benzylamino)phosphonium chloride
title_full Tetrakis(benzylamino)phosphonium chloride
title_fullStr Tetrakis(benzylamino)phosphonium chloride
title_full_unstemmed Tetrakis(benzylamino)phosphonium chloride
title_sort tetrakis(benzylamino)phosphonium chloride
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-02-01
description The title salt, [P(NHCH2C6H5)4]+·Cl−, crystallizes with the P atom and Cl− anion lying on a twofold rotation axis. The P atom has a slightly distorted tetrahedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environments of sp2-hybridized N atoms are essentially planar (sum of angles = 359.9 and 360.1°). In the crystal, the phosphonium ion interacts with each neighboring chloride ion via two approximately equal N—H...Cl interactions, forming parallel chains along the c axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810054401
work_keys_str_mv AT khodayargholivand tetrakisbenzylaminophosphoniumchloride
AT hosseinmostaanzadeh tetrakisbenzylaminophosphoniumchloride
AT sedighehfarshadian tetrakisbenzylaminophosphoniumchloride
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