A boron-based electrolyte additive for calcium electrodeposition
In recent years, several organic electrolytes have been reported allowing calcium metal electrodeposition. In all cases, some degree of passivation on the surface of the calcium electrode was reported. Following a recent report on borate-based passivation layer playing a crucial role for Ca plating...
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2021-03-01
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doaj-f247e2036e03481c9a28c30c5f2df1d92021-03-11T04:24:16ZengElsevierElectrochemistry Communications1388-24812021-03-01124106936A boron-based electrolyte additive for calcium electrodepositionJuan Forero-Saboya0Charlotte Bodin1Alexandre Ponrouch2Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193 Bellaterra, SpainInstitut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193 Bellaterra, Spain; ALISTORE, European Research Institute, CNRS FR 3104, Hub de l’Energie, 80039 Amiens, FranceInstitut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193 Bellaterra, Spain; ALISTORE, European Research Institute, CNRS FR 3104, Hub de l’Energie, 80039 Amiens, France; Corresponding author.In recent years, several organic electrolytes have been reported allowing calcium metal electrodeposition. In all cases, some degree of passivation on the surface of the calcium electrode was reported. Following a recent report on borate-based passivation layer playing a crucial role for Ca plating in electrolyte solutions containing Ca(BF4)2, here we report the use of a boron-containing additive. The presence of this additive allows Ca plating and stripping using a Ca(TFSI)2 containing electrolyte, which otherwise lead to the formation of a fully Ca2+ blocking passivation layer.http://www.sciencedirect.com/science/article/pii/S1388248121000205Calcium batteriesBoron-containing additiveCalcium platingMetal anode |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Juan Forero-Saboya Charlotte Bodin Alexandre Ponrouch |
spellingShingle |
Juan Forero-Saboya Charlotte Bodin Alexandre Ponrouch A boron-based electrolyte additive for calcium electrodeposition Electrochemistry Communications Calcium batteries Boron-containing additive Calcium plating Metal anode |
author_facet |
Juan Forero-Saboya Charlotte Bodin Alexandre Ponrouch |
author_sort |
Juan Forero-Saboya |
title |
A boron-based electrolyte additive for calcium electrodeposition |
title_short |
A boron-based electrolyte additive for calcium electrodeposition |
title_full |
A boron-based electrolyte additive for calcium electrodeposition |
title_fullStr |
A boron-based electrolyte additive for calcium electrodeposition |
title_full_unstemmed |
A boron-based electrolyte additive for calcium electrodeposition |
title_sort |
boron-based electrolyte additive for calcium electrodeposition |
publisher |
Elsevier |
series |
Electrochemistry Communications |
issn |
1388-2481 |
publishDate |
2021-03-01 |
description |
In recent years, several organic electrolytes have been reported allowing calcium metal electrodeposition. In all cases, some degree of passivation on the surface of the calcium electrode was reported. Following a recent report on borate-based passivation layer playing a crucial role for Ca plating in electrolyte solutions containing Ca(BF4)2, here we report the use of a boron-containing additive. The presence of this additive allows Ca plating and stripping using a Ca(TFSI)2 containing electrolyte, which otherwise lead to the formation of a fully Ca2+ blocking passivation layer. |
topic |
Calcium batteries Boron-containing additive Calcium plating Metal anode |
url |
http://www.sciencedirect.com/science/article/pii/S1388248121000205 |
work_keys_str_mv |
AT juanforerosaboya aboronbasedelectrolyteadditiveforcalciumelectrodeposition AT charlottebodin aboronbasedelectrolyteadditiveforcalciumelectrodeposition AT alexandreponrouch aboronbasedelectrolyteadditiveforcalciumelectrodeposition AT juanforerosaboya boronbasedelectrolyteadditiveforcalciumelectrodeposition AT charlottebodin boronbasedelectrolyteadditiveforcalciumelectrodeposition AT alexandreponrouch boronbasedelectrolyteadditiveforcalciumelectrodeposition |
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1724226079119376384 |