2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3)
The asymmetric unit of the 5:3 title co-crystal of 2-amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile and 3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile, 0.625C20H15N3.0.375C22H15N3, has the atoms of the fused-ring system and those of the amino, cyano and phenyl substitutents...
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| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811040505 |
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doaj-f19df9f52f0d4858a3fcb98cbfb6d8002020-11-24T21:53:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711o2872o287210.1107/S16005368110405052-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3)Abdullah M. AsiriAbdulrahman O. Al-YoubiHassan M. FaidallahSeik Weng NgThe asymmetric unit of the 5:3 title co-crystal of 2-amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile and 3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile, 0.625C20H15N3.0.375C22H15N3, has the atoms of the fused-ring system and those of the amino, cyano and phenyl substitutents overlapped. The fused-ring system is buckled owing to the ethylene linkage in the central ring, the two flanking aromatic rings being twisted by 20.1 (1)°. This ethylene portion is disordered over two positions in a 1:1 ratio. The phenyl ring is twisted by 69.5 (1)° relative to the amino- and cyano-bearing aromatic ring. In the crystal, two molecules are linked by an N—H...N hydrogen bond, generating a a helical chain along [010].http://scripts.iucr.org/cgi-bin/paper?S1600536811040505 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Abdullah M. Asiri Abdulrahman O. Al-Youbi Hassan M. Faidallah Seik Weng Ng |
| spellingShingle |
Abdullah M. Asiri Abdulrahman O. Al-Youbi Hassan M. Faidallah Seik Weng Ng 2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) Acta Crystallographica Section E |
| author_facet |
Abdullah M. Asiri Abdulrahman O. Al-Youbi Hassan M. Faidallah Seik Weng Ng |
| author_sort |
Abdullah M. Asiri |
| title |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| title_short |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| title_full |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| title_fullStr |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| title_full_unstemmed |
2-Amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| title_sort |
2-amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile–3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile (5/3) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-11-01 |
| description |
The asymmetric unit of the 5:3 title co-crystal of 2-amino-4-phenyl-5,6-dihydrobenzo[h]quinoline-3-carbonitrile and 3-amino-1-phenyl-9,10-dihydrophenanthrene-2,4-dicarbonitrile, 0.625C20H15N3.0.375C22H15N3, has the atoms of the fused-ring system and those of the amino, cyano and phenyl substitutents overlapped. The fused-ring system is buckled owing to the ethylene linkage in the central ring, the two flanking aromatic rings being twisted by 20.1 (1)°. This ethylene portion is disordered over two positions in a 1:1 ratio. The phenyl ring is twisted by 69.5 (1)° relative to the amino- and cyano-bearing aromatic ring. In the crystal, two molecules are linked by an N—H...N hydrogen bond, generating a a helical chain along [010]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811040505 |
| work_keys_str_mv |
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