Hydrogels as Porogens for Nanoporous Inorganic Materials

Organic polymer-hydrogels are known to be capable of directing the nucleation and growth of inorganic materials, such as silica, metal oxides, apatite or metal chalcogenides. This approach can be exploited in the synthesis of materials that exhibit defined nanoporosity. When the organic polymer-base...

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Main Authors: Christian Weinberger, Dirk Kuckling, Michael Tiemann
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Gels
Subjects:
Online Access:http://www.mdpi.com/2310-2861/4/4/83
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spelling doaj-f17c7f6a1c9843898da7d6c683ac150b2020-11-24T21:27:50ZengMDPI AGGels2310-28612018-10-01448310.3390/gels4040083gels4040083Hydrogels as Porogens for Nanoporous Inorganic MaterialsChristian Weinberger0Dirk Kuckling1Michael Tiemann2Department of Chemistry—Inorganic Functional Materials, Paderborn University, 33098 Paderborn, GermanyDepartment of Chemistry—Organic and Macromolecular Chemistry, Paderborn University, 33098 Paderborn, GermanyDepartment of Chemistry—Inorganic Functional Materials, Paderborn University, 33098 Paderborn, GermanyOrganic polymer-hydrogels are known to be capable of directing the nucleation and growth of inorganic materials, such as silica, metal oxides, apatite or metal chalcogenides. This approach can be exploited in the synthesis of materials that exhibit defined nanoporosity. When the organic polymer-based hydrogel is incorporated in the inorganic product, a composite is formed from which the organic component may be selectively removed, yielding nanopores in the inorganic product. Such porogenic impact resembles the concept of using soft or hard templates for porous materials. This micro-review provides a survey of select examples from the literature.http://www.mdpi.com/2310-2861/4/4/83nanoporousmesoporousmetal oxidesilicahydrogelthin filmporogentemplatenanocasting
collection DOAJ
language English
format Article
sources DOAJ
author Christian Weinberger
Dirk Kuckling
Michael Tiemann
spellingShingle Christian Weinberger
Dirk Kuckling
Michael Tiemann
Hydrogels as Porogens for Nanoporous Inorganic Materials
Gels
nanoporous
mesoporous
metal oxide
silica
hydrogel
thin film
porogen
template
nanocasting
author_facet Christian Weinberger
Dirk Kuckling
Michael Tiemann
author_sort Christian Weinberger
title Hydrogels as Porogens for Nanoporous Inorganic Materials
title_short Hydrogels as Porogens for Nanoporous Inorganic Materials
title_full Hydrogels as Porogens for Nanoporous Inorganic Materials
title_fullStr Hydrogels as Porogens for Nanoporous Inorganic Materials
title_full_unstemmed Hydrogels as Porogens for Nanoporous Inorganic Materials
title_sort hydrogels as porogens for nanoporous inorganic materials
publisher MDPI AG
series Gels
issn 2310-2861
publishDate 2018-10-01
description Organic polymer-hydrogels are known to be capable of directing the nucleation and growth of inorganic materials, such as silica, metal oxides, apatite or metal chalcogenides. This approach can be exploited in the synthesis of materials that exhibit defined nanoporosity. When the organic polymer-based hydrogel is incorporated in the inorganic product, a composite is formed from which the organic component may be selectively removed, yielding nanopores in the inorganic product. Such porogenic impact resembles the concept of using soft or hard templates for porous materials. This micro-review provides a survey of select examples from the literature.
topic nanoporous
mesoporous
metal oxide
silica
hydrogel
thin film
porogen
template
nanocasting
url http://www.mdpi.com/2310-2861/4/4/83
work_keys_str_mv AT christianweinberger hydrogelsasporogensfornanoporousinorganicmaterials
AT dirkkuckling hydrogelsasporogensfornanoporousinorganicmaterials
AT michaeltiemann hydrogelsasporogensfornanoporousinorganicmaterials
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