2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate

2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate

In the title compound, C35H36N2O5·0.5C4H10O, the asymmetric unit contains one bicyclo[3.3.1]nonane molecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intramolecular N—H...O hydrogen bonds generate S(6) ring...

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Main Authors: Hoong-Kun Fun, Chin Sing Yeap, K. Rajesh, S. Sarveswari, V. Vijayakumar
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809036733
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spelling doaj-f17a660be08444a0a75f993e88f95eb02020-11-24T21:55:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510o2486o248710.1107/S16005368090367332,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvateHoong-Kun FunChin Sing YeapK. RajeshS. SarveswariV. VijayakumarIn the title compound, C35H36N2O5·0.5C4H10O, the asymmetric unit contains one bicyclo[3.3.1]nonane molecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intramolecular N—H...O hydrogen bonds generate S(6) ring motifs. The bicyclo[3.3.1]nonane ring system adopts a chair-boat conformation. In the crystal structure, the molecules are linked by weak intermolecular C—H...N hydrogen bonds into chains along the b axis; additional stabilization is provide by C—H...π interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536809036733
collection DOAJ
language English
format Article
sources DOAJ
author Hoong-Kun Fun
Chin Sing Yeap
K. Rajesh
S. Sarveswari
V. Vijayakumar
spellingShingle Hoong-Kun Fun
Chin Sing Yeap
K. Rajesh
S. Sarveswari
V. Vijayakumar
2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
Acta Crystallographica Section E
author_facet Hoong-Kun Fun
Chin Sing Yeap
K. Rajesh
S. Sarveswari
V. Vijayakumar
author_sort Hoong-Kun Fun
title 2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
title_short 2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
title_full 2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
title_fullStr 2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
title_full_unstemmed 2,4,6,8-Tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
title_sort 2,4,6,8-tetrakis(2-methoxyphenyl)-3,7-diazabicyclo[3.3.1]nonan-9-one diethyl ether hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description In the title compound, C35H36N2O5·0.5C4H10O, the asymmetric unit contains one bicyclo[3.3.1]nonane molecule and a half-occupancy diethyl ether solvent with the O atom lying on a crystallographic inversion center. Two intramolecular N—H...O hydrogen bonds generate S(6) ring motifs. The bicyclo[3.3.1]nonane ring system adopts a chair-boat conformation. In the crystal structure, the molecules are linked by weak intermolecular C—H...N hydrogen bonds into chains along the b axis; additional stabilization is provide by C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809036733
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AT krajesh 2468tetrakis2methoxyphenyl37diazabicyclo331nonan9onediethyletherhemisolvate
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