Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells

In this study, a unique approach was developed to synthesize 1-D core-shell nanofibers of carbon nanotubes (CNTs) and TiO2 using combination of coaxial electrospinning and sol-gel technique. Diameters of the fabricated core-shell single wall ca...

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Main Authors: Y. Shabdan, A. Ronasi, P. Coulibaly, M. Moniruddin, N. Nuraje
Format: Article
Language:English
Published: AIP Publishing LLC 2017-06-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4983181
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spelling doaj-f128306ea2f740499ff4658a26bb41c32020-11-24T21:13:28ZengAIP Publishing LLCAIP Advances2158-32262017-06-0176065008065008-710.1063/1.4983181009705ADVEngineered core-shell nanofibers for electron transport study in dye-sensitized solar cellsY. Shabdan0A. Ronasi1P. Coulibaly2M. Moniruddin3N. Nuraje4Department of Physics and Technology, Al-Farabi Kazakh National University, Almaty, KazakhstanDepartment of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409, USADepartment of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409, USADepartment of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409, USADepartment of Chemical Engineering, Texas Tech University, Lubbock, Texas 79409, USAIn this study, a unique approach was developed to synthesize 1-D core-shell nanofibers of carbon nanotubes (CNTs) and TiO2 using combination of coaxial electrospinning and sol-gel technique. Diameters of the fabricated core-shell single wall carbon nanotube-TiO2 (SWCNT-TiO2) and multi wall carbon nanotube-TiO2 (MWCNT-TiO2) nano-composite fibers were between 50-100nm. Energy dispersive spectroscopy (EDS) and X-ray photon spectroscopy (XPS) were applied to confirm encapsulation of carbon nanotube (CNT) in the core-shell structure. Electron transport properties of both SWCNT-TiO2 and MWCNT-TiO2 in the Dye-sensitized solar cells (DSSCs) were studied for the first time. It was found that SWCNT-TiO2 based DSSC provided higher short circuit current relative to MWCNT-TiO2, which was explained by I-V and bode plots. These findings were further illustrated by semi-conductive properties of SWCNT.http://dx.doi.org/10.1063/1.4983181
collection DOAJ
language English
format Article
sources DOAJ
author Y. Shabdan
A. Ronasi
P. Coulibaly
M. Moniruddin
N. Nuraje
spellingShingle Y. Shabdan
A. Ronasi
P. Coulibaly
M. Moniruddin
N. Nuraje
Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
AIP Advances
author_facet Y. Shabdan
A. Ronasi
P. Coulibaly
M. Moniruddin
N. Nuraje
author_sort Y. Shabdan
title Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
title_short Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
title_full Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
title_fullStr Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
title_full_unstemmed Engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
title_sort engineered core-shell nanofibers for electron transport study in dye-sensitized solar cells
publisher AIP Publishing LLC
series AIP Advances
issn 2158-3226
publishDate 2017-06-01
description In this study, a unique approach was developed to synthesize 1-D core-shell nanofibers of carbon nanotubes (CNTs) and TiO2 using combination of coaxial electrospinning and sol-gel technique. Diameters of the fabricated core-shell single wall carbon nanotube-TiO2 (SWCNT-TiO2) and multi wall carbon nanotube-TiO2 (MWCNT-TiO2) nano-composite fibers were between 50-100nm. Energy dispersive spectroscopy (EDS) and X-ray photon spectroscopy (XPS) were applied to confirm encapsulation of carbon nanotube (CNT) in the core-shell structure. Electron transport properties of both SWCNT-TiO2 and MWCNT-TiO2 in the Dye-sensitized solar cells (DSSCs) were studied for the first time. It was found that SWCNT-TiO2 based DSSC provided higher short circuit current relative to MWCNT-TiO2, which was explained by I-V and bode plots. These findings were further illustrated by semi-conductive properties of SWCNT.
url http://dx.doi.org/10.1063/1.4983181
work_keys_str_mv AT yshabdan engineeredcoreshellnanofibersforelectrontransportstudyindyesensitizedsolarcells
AT aronasi engineeredcoreshellnanofibersforelectrontransportstudyindyesensitizedsolarcells
AT pcoulibaly engineeredcoreshellnanofibersforelectrontransportstudyindyesensitizedsolarcells
AT mmoniruddin engineeredcoreshellnanofibersforelectrontransportstudyindyesensitizedsolarcells
AT nnuraje engineeredcoreshellnanofibersforelectrontransportstudyindyesensitizedsolarcells
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