Self-organized internal architectures of chiral micro-particles

The internal architecture of polymeric self-assembled chiral micro-particles is studied by exploring the effect of the chirality, of the particle sizes, and of the interface/surface properties in the ordering of the helicoidal planes. The experimental investigations, performed by means of different...

Full description

Bibliographic Details
Main Authors: Clementina Provenzano, Alfredo Mazzulla, Pasquale Pagliusi, Maria P. De Santo, Giovanni Desiderio, Ida Perrotta, Gabriella Cipparrone
Format: Article
Language:English
Published: AIP Publishing LLC 2014-02-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4863837
id doaj-f0c14a096bef4df885caa4b5287b897e
record_format Article
spelling doaj-f0c14a096bef4df885caa4b5287b897e2020-11-24T23:39:30ZengAIP Publishing LLCAPL Materials2166-532X2014-02-0122022103022103-710.1063/1.4863837004402APMSelf-organized internal architectures of chiral micro-particlesClementina Provenzano0Alfredo Mazzulla1Pasquale Pagliusi2Maria P. De Santo3Giovanni Desiderio4Ida Perrotta5Gabriella Cipparrone6Physics Department, University of Calabria, 87036 Rende, CS, ItalyCNR-IPCF, UOS Cosenza, 87036 Rende, CS, ItalyPhysics Department, University of Calabria, 87036 Rende, CS, ItalyPhysics Department, University of Calabria, 87036 Rende, CS, ItalyCNR-IPCF, UOS Cosenza, 87036 Rende, CS, ItalyBiology, Ecology and Earth Sciences (Di.B.E.S.T.) Department, University of Calabria, 87036 Rende, CS, ItalyPhysics Department, University of Calabria, 87036 Rende, CS, ItalyThe internal architecture of polymeric self-assembled chiral micro-particles is studied by exploring the effect of the chirality, of the particle sizes, and of the interface/surface properties in the ordering of the helicoidal planes. The experimental investigations, performed by means of different microscopy techniques, show that the polymeric beads, resulting from light induced polymerization of cholesteric liquid crystal droplets, preserve both the spherical shape and the internal self-organized structures. The method used to create the micro-particles with controlled internal chiral architectures presents great flexibility providing several advantages connected to the acquired optical and photonics capabilities and allowing to envisage novel strategies for the development of chiral colloidal systems and materials.http://dx.doi.org/10.1063/1.4863837
collection DOAJ
language English
format Article
sources DOAJ
author Clementina Provenzano
Alfredo Mazzulla
Pasquale Pagliusi
Maria P. De Santo
Giovanni Desiderio
Ida Perrotta
Gabriella Cipparrone
spellingShingle Clementina Provenzano
Alfredo Mazzulla
Pasquale Pagliusi
Maria P. De Santo
Giovanni Desiderio
Ida Perrotta
Gabriella Cipparrone
Self-organized internal architectures of chiral micro-particles
APL Materials
author_facet Clementina Provenzano
Alfredo Mazzulla
Pasquale Pagliusi
Maria P. De Santo
Giovanni Desiderio
Ida Perrotta
Gabriella Cipparrone
author_sort Clementina Provenzano
title Self-organized internal architectures of chiral micro-particles
title_short Self-organized internal architectures of chiral micro-particles
title_full Self-organized internal architectures of chiral micro-particles
title_fullStr Self-organized internal architectures of chiral micro-particles
title_full_unstemmed Self-organized internal architectures of chiral micro-particles
title_sort self-organized internal architectures of chiral micro-particles
publisher AIP Publishing LLC
series APL Materials
issn 2166-532X
publishDate 2014-02-01
description The internal architecture of polymeric self-assembled chiral micro-particles is studied by exploring the effect of the chirality, of the particle sizes, and of the interface/surface properties in the ordering of the helicoidal planes. The experimental investigations, performed by means of different microscopy techniques, show that the polymeric beads, resulting from light induced polymerization of cholesteric liquid crystal droplets, preserve both the spherical shape and the internal self-organized structures. The method used to create the micro-particles with controlled internal chiral architectures presents great flexibility providing several advantages connected to the acquired optical and photonics capabilities and allowing to envisage novel strategies for the development of chiral colloidal systems and materials.
url http://dx.doi.org/10.1063/1.4863837
work_keys_str_mv AT clementinaprovenzano selforganizedinternalarchitecturesofchiralmicroparticles
AT alfredomazzulla selforganizedinternalarchitecturesofchiralmicroparticles
AT pasqualepagliusi selforganizedinternalarchitecturesofchiralmicroparticles
AT mariapdesanto selforganizedinternalarchitecturesofchiralmicroparticles
AT giovannidesiderio selforganizedinternalarchitecturesofchiralmicroparticles
AT idaperrotta selforganizedinternalarchitecturesofchiralmicroparticles
AT gabriellacipparrone selforganizedinternalarchitecturesofchiralmicroparticles
_version_ 1725513167030714368