Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane

Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane

The AuI atom in the title compound, [Au(C21H24N2)2](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3&...

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Main Authors: Lennart Möhlmann, Ola F. Wendt, Magnus T. Johnson
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811016357
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spelling doaj-f0b9787fcf294570aa6088984f532cf72020-11-25T00:55:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m719m72010.1107/S1600536811016357Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecaneLennart MöhlmannOla F. WendtMagnus T. JohnsonThe AuI atom in the title compound, [Au(C21H24N2)2](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)°. In the crystal, the components are linked by weak C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811016357
collection DOAJ
language English
format Article
sources DOAJ
author Lennart Möhlmann
Ola F. Wendt
Magnus T. Johnson
spellingShingle Lennart Möhlmann
Ola F. Wendt
Magnus T. Johnson
Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
Acta Crystallographica Section E
author_facet Lennart Möhlmann
Ola F. Wendt
Magnus T. Johnson
author_sort Lennart Möhlmann
title Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
title_short Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
title_full Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
title_fullStr Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
title_full_unstemmed Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
title_sort bis(1,3-dimesitylimidazolyl)gold(i) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspiro[5.5]undecane
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description The AuI atom in the title compound, [Au(C21H24N2)2](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)°. In the crystal, the components are linked by weak C—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811016357
work_keys_str_mv AT lennartmamp246hlmann bis13dimesitylimidazolylgoldi24810tetraphenyl1357911hexaoxa24810tetrabora6borataspiro55undecane
AT olafwendt bis13dimesitylimidazolylgoldi24810tetraphenyl1357911hexaoxa24810tetrabora6borataspiro55undecane
AT magnustjohnson bis13dimesitylimidazolylgoldi24810tetraphenyl1357911hexaoxa24810tetrabora6borataspiro55undecane
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