Aqua(1,10-phenanthroline-κ2N,N′)bis(trimethylacetato)-κ2O,O′;κO-cobalt(II)

Aqua(1,10-phenanthroline-κ2N,N′)bis(trimethylacetato)-κ2O,O′;κO-cobalt(II)

In the title compound, [Co(C5H9O2)2(C12H8N2)(H2O)], the CoII atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O—H...O hyd...

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Bibliographic Details
Main Authors: Xiao-Dan Chen, Hong-Xian Chen, Zhong-Shu Li, Huai-Hong Zhang, Bai-Wang Sun
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809027251
Description
Summary:In the title compound, [Co(C5H9O2)2(C12H8N2)(H2O)], the CoII atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O—H...O hydrogen bonds and π–π stacking interactions [interplanar distance between interdigitating 1,10-phenanthroline ligands = 3.523 (2) Å].
ISSN:1600-5368

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