trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)

trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)

The title compound, [Re(C2H5O)Cl2O(C7H9N)2], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex molecules are linked by weak C&am...

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Main Authors: Anna Skarżyńska, Anna M. Trzeciak, Andrzej Gniewek
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811029588
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spelling doaj-f0686b47de72449db86fa5059a49b7b02020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1154m115510.1107/S1600536811029588trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)Anna SkarżyńskaAnna M. TrzeciakAndrzej GniewekThe title compound, [Re(C2H5O)Cl2O(C7H9N)2], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex molecules are linked by weak C—H...Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking interactions between the aromatic rings with centroid–centroid distances of 3.546 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536811029588
collection DOAJ
language English
format Article
sources DOAJ
author Anna Skarżyńska
Anna M. Trzeciak
Andrzej Gniewek
spellingShingle Anna Skarżyńska
Anna M. Trzeciak
Andrzej Gniewek
trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
Acta Crystallographica Section E
author_facet Anna Skarżyńska
Anna M. Trzeciak
Andrzej Gniewek
author_sort Anna Skarżyńska
title trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
title_short trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
title_full trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
title_fullStr trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
title_full_unstemmed trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
title_sort trans-dichloridobis(3,5-dimethylpyridine-κn)(ethanolato-κo)oxidorhenium(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-08-01
description The title compound, [Re(C2H5O)Cl2O(C7H9N)2], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex molecules are linked by weak C—H...Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking interactions between the aromatic rings with centroid–centroid distances of 3.546 (4) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811029588
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AT annamtrzeciak transdichloridobis35dimethylpyridineamp954nethanolatoamp954ooxidorheniumv
AT andrzejgniewek transdichloridobis35dimethylpyridineamp954nethanolatoamp954ooxidorheniumv
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