trans-Dichloridobis(3,5-dimethylpyridine-κN)(ethanolato-κO)oxidorhenium(V)
The title compound, [Re(C2H5O)Cl2O(C7H9N)2], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex molecules are linked by weak C&am...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811029588 |
| Summary: | The title compound, [Re(C2H5O)Cl2O(C7H9N)2], was crystallized from ethanol. The crystal structure of this complex contains a Re(V) atom in a slightly distorted octahedral coordination geometry with pairs of equivalent ligands in trans positions. Adjacent complex molecules are linked by weak C—H...Cl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking interactions between the aromatic rings with centroid–centroid distances of 3.546 (4) Å. |
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| ISSN: | 1600-5368 |