Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis

The aliphatic-aromatic copolyester poly(butylene adipate-co-butylene terephthalate) (PBAT), also known as ecoflex, contains adipic acid, 1,4-butanediol and terephthalic acid and is proven to be compostable [1–3]). We describe here data for the synthesis and analysis of poly(butylene adipate-co-butyl...

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Main Authors: Veronika Perz, Klaus Bleymaier, Carsten Sinkel, Ulf Kueper, Melanie Bonnekessel, Doris Ribitsch, Georg M. Guebitz
Format: Article
Language:English
Published: Elsevier 2016-06-01
Series:Data in Brief
Online Access:http://www.sciencedirect.com/science/article/pii/S2352340916300518
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spelling doaj-efa30249117244f18b4710eb75400dd32020-11-25T02:40:01ZengElsevierData in Brief2352-34092016-06-017291298Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysisVeronika Perz0Klaus Bleymaier1Carsten Sinkel2Ulf Kueper3Melanie Bonnekessel4Doris Ribitsch5Georg M. Guebitz6acib – Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln, Austriaacib – Austrian Centre of Industrial Biotechnology, Petersgasse 14, 8010 Graz, AustriaBASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen, GermanyBASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen, GermanyBASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen, Germanyacib – Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln, Austria; Institute of Environmental Biotechnology, University of Natural Resources and Life Sciences, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, Austria; Corresponding author at: acib – Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln, Austria. Tel.: +43 1 47654 4974.acib – Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln, Austria; Institute of Environmental Biotechnology, University of Natural Resources and Life Sciences, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, AustriaThe aliphatic-aromatic copolyester poly(butylene adipate-co-butylene terephthalate) (PBAT), also known as ecoflex, contains adipic acid, 1,4-butanediol and terephthalic acid and is proven to be compostable [1–3]). We describe here data for the synthesis and analysis of poly(butylene adipate-co-butylene terephthalate variants with different adipic acid:terephatalic acid ratios and 6 oligomeric PBAT model substrates. Data for the synthesis of the following oligomeric model substrates are described: mono(4-hydroxybutyl) terephthalate (BTa), bis(4-(hexanoyloxy)butyl) terephthalate (HaBTaBHa), bis(4-(decanoyloxy)butyl) terephthalate (DaBTaBDa), bis(4-(tetradecanoyloxy)butyl) terephthalate (TdaBTaBTda), bis(4-hydroxyhexyl) terephthalate (HTaH) and bis(4-(benzoyloxy)butyl) terephthalate (BaBTaBBa). Polymeric PBAT variants were synthesized with adipic acid:terephatalic acid ratios of 100:0, 90:10, 80:20, 70:30, 60:40 and 50:50. These polymeric and oligomeric substances were used as ecoflex model substrates in enzymatic hydrolysis experiments in the article “Substrate specificities of cutinases on aliphatic-aromatic polyesters and on their model substrates” [4]. Keywords: Oligomer synthesis, Oligomer analysis, Polyester model substrateshttp://www.sciencedirect.com/science/article/pii/S2352340916300518
collection DOAJ
language English
format Article
sources DOAJ
author Veronika Perz
Klaus Bleymaier
Carsten Sinkel
Ulf Kueper
Melanie Bonnekessel
Doris Ribitsch
Georg M. Guebitz
spellingShingle Veronika Perz
Klaus Bleymaier
Carsten Sinkel
Ulf Kueper
Melanie Bonnekessel
Doris Ribitsch
Georg M. Guebitz
Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
Data in Brief
author_facet Veronika Perz
Klaus Bleymaier
Carsten Sinkel
Ulf Kueper
Melanie Bonnekessel
Doris Ribitsch
Georg M. Guebitz
author_sort Veronika Perz
title Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
title_short Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
title_full Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
title_fullStr Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
title_full_unstemmed Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
title_sort data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis
publisher Elsevier
series Data in Brief
issn 2352-3409
publishDate 2016-06-01
description The aliphatic-aromatic copolyester poly(butylene adipate-co-butylene terephthalate) (PBAT), also known as ecoflex, contains adipic acid, 1,4-butanediol and terephthalic acid and is proven to be compostable [1–3]). We describe here data for the synthesis and analysis of poly(butylene adipate-co-butylene terephthalate variants with different adipic acid:terephatalic acid ratios and 6 oligomeric PBAT model substrates. Data for the synthesis of the following oligomeric model substrates are described: mono(4-hydroxybutyl) terephthalate (BTa), bis(4-(hexanoyloxy)butyl) terephthalate (HaBTaBHa), bis(4-(decanoyloxy)butyl) terephthalate (DaBTaBDa), bis(4-(tetradecanoyloxy)butyl) terephthalate (TdaBTaBTda), bis(4-hydroxyhexyl) terephthalate (HTaH) and bis(4-(benzoyloxy)butyl) terephthalate (BaBTaBBa). Polymeric PBAT variants were synthesized with adipic acid:terephatalic acid ratios of 100:0, 90:10, 80:20, 70:30, 60:40 and 50:50. These polymeric and oligomeric substances were used as ecoflex model substrates in enzymatic hydrolysis experiments in the article “Substrate specificities of cutinases on aliphatic-aromatic polyesters and on their model substrates” [4]. Keywords: Oligomer synthesis, Oligomer analysis, Polyester model substrates
url http://www.sciencedirect.com/science/article/pii/S2352340916300518
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