Investigation on third-order nonlinear parameters, mechanical and dielectric behavior of alkali metal-organic C2HLiO4 H2O single crystal

• Main Authors: D.S. Ajisha, R. Ezhil Vizhi
• Format: Article
• Language: English
• Published: Elsevier 2021-07-01
• Series: Results in Physics
• Subjects: Metal-organic crystal; Z-scan; Solution growth; Hardness number; Third-order nonlinear parameters; Dielectric analysis
• Online Access: http://www.sciencedirect.com/science/article/pii/S2211379721005064

A metal-organic lithium hydrogen oxalate hydrate single crystal was developed using the solution growth method. The single-crystal XRD analysis confirmed the triclinic structure and space group P1 along with the lattice parameters a = 3.439 Å, b = 5.097 Å, c = 6.141 Å, α = 78.50°, β = 84.89°, and γ = 81.41° of the grown crystal. The average crystallite size and strain within the material were calculated and compared using Debye Scherrer and Williamson-Hall method. The existence of diverse functional groups in the LHOH crystal was verified with the help of the FTIR analysis. The Z-scan method was carried out to acquire information about the developed material's third-order nonlinear characteristics that showed the material's self-focusing effect. The dielectric behavior of the compound was studied for various temperatures and frequencies. The Vicker’s microhardness analysis was carried out to collect information about the hardness number, yield strength, elastic stiffness, brittle index and fracture toughness of the grown crystal. The hardness number decreased when the applied load was increased, which indicated the normal indentation effect of the material.