One-pot formation of 2,4-di- or 2,4,6-tri-olefinic monocarboxylic acids by straight chain C4-extension

One-pot formation of 2,4-di- or 2,4,6-tri-olefinic monocarboxylic acids by straight chain C4-extension

We report a one-pot formation of 2,4-diolefinic or 2,4,6-triolefinic monocarboxylic acids, R-(CHCH)2or3-COOH, by decarboxylative condensation of an optionally α,β-unsaturated aldehyde with glutaconic acid, HOOC-CH2-CHCH-COOH as straight chain C4-extender. The reaction is broadly applicable to satu...

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Bibliographic Details
Main Authors: Jessica Sobotta, Maximilian Schmalhofer, Thomas M. Steiner, Wolfgang Eisenreich, Günter Wächtershäuser, Claudia Huber
Format: Article
Language:English
Published: Elsevier 2017-07-01
Series:Heliyon
Subjects:
Organic chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844017303535

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