Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]

Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]

The title three-dimensional coordination network, {[Dy(C4H4N2O2)4](ClO4)3}n, is isostructural of other lanthanides. The Dy+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′-dioxide...

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Main Authors: Benjamin G. Quinn-Elmore, James D. Buchner, Keith B. Beach, Jacqueline M. Knaust
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681003182X
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spelling doaj-ef7c933caa3d4b008a78c0ee861698052020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1106m110710.1107/S160053681003182XPoly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]Benjamin G. Quinn-ElmoreJames D. BuchnerKeith B. BeachJacqueline M. KnaustThe title three-dimensional coordination network, {[Dy(C4H4N2O2)4](ClO4)3}n, is isostructural of other lanthanides. The Dy+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′-dioxide ligands. There are two unique pyrazine N,N′-dioxide ligands. One ring is located around an inversion center, and there is a a twofold rotation axis at the center of the other ring. There are also two unique perchlorate anions. One is centered on a twofold rotation axis and the other on a fourfold roto-inversion axis. The perchlorate anions are located in channels that run perpendicular to (001) and (110) and interact with the coordination network through C—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S160053681003182X
collection DOAJ
language English
format Article
sources DOAJ
author Benjamin G. Quinn-Elmore
James D. Buchner
Keith B. Beach
Jacqueline M. Knaust
spellingShingle Benjamin G. Quinn-Elmore
James D. Buchner
Keith B. Beach
Jacqueline M. Knaust
Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
Acta Crystallographica Section E
author_facet Benjamin G. Quinn-Elmore
James D. Buchner
Keith B. Beach
Jacqueline M. Knaust
author_sort Benjamin G. Quinn-Elmore
title Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
title_short Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
title_full Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
title_fullStr Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
title_full_unstemmed Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)dysprosium(III)] tris(perchlorate)]
title_sort poly[[tetrakis(μ2-pyrazine n,n′-dioxide-κ2o:o′)dysprosium(iii)] tris(perchlorate)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description The title three-dimensional coordination network, {[Dy(C4H4N2O2)4](ClO4)3}n, is isostructural of other lanthanides. The Dy+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′-dioxide ligands. There are two unique pyrazine N,N′-dioxide ligands. One ring is located around an inversion center, and there is a a twofold rotation axis at the center of the other ring. There are also two unique perchlorate anions. One is centered on a twofold rotation axis and the other on a fourfold roto-inversion axis. The perchlorate anions are located in channels that run perpendicular to (001) and (110) and interact with the coordination network through C—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S160053681003182X
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AT jamesdbuchner polytetrakisamp9562pyrazinennamp8242dioxideamp9542ooamp8242dysprosiumiiitrisperchlorate
AT keithbbeach polytetrakisamp9562pyrazinennamp8242dioxideamp9542ooamp8242dysprosiumiiitrisperchlorate
AT jacquelinemknaust polytetrakisamp9562pyrazinennamp8242dioxideamp9542ooamp8242dysprosiumiiitrisperchlorate
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