The moment of initial crystallization captured on functionalized nanoparticles

Understanding the mechanism of supercooling suppression by crystallization seeds is important for designing semiclathrate hydrates for latent heat storage materials. Here, we show that 10-30 nm cluster formation around silver nanoparticles promotes crystallization of supercooled aqueous solutions.

Bibliographic Details
Main Authors: Hironobu Machida, Takeshi Sugahara, Izumi Hirasawa
Format: Article
Language:English
Published: Nature Publishing Group 2021-06-01
Series:Communications Materials
Online Access:https://doi.org/10.1038/s43246-021-00171-w
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spelling doaj-ef05c4331bb64e72aefef0ddaa5248972021-06-20T11:19:44ZengNature Publishing GroupCommunications Materials2662-44432021-06-01211710.1038/s43246-021-00171-wThe moment of initial crystallization captured on functionalized nanoparticlesHironobu Machida0Takeshi Sugahara1Izumi Hirasawa2Corporate Engineering Division, Appliances Company, Panasonic CorporationDivision of Chemical Engineering, Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka UniversityDepartment of Applied Chemistry, Waseda UniversityUnderstanding the mechanism of supercooling suppression by crystallization seeds is important for designing semiclathrate hydrates for latent heat storage materials. Here, we show that 10-30 nm cluster formation around silver nanoparticles promotes crystallization of supercooled aqueous solutions.https://doi.org/10.1038/s43246-021-00171-w
collection DOAJ
language English
format Article
sources DOAJ
author Hironobu Machida
Takeshi Sugahara
Izumi Hirasawa
spellingShingle Hironobu Machida
Takeshi Sugahara
Izumi Hirasawa
The moment of initial crystallization captured on functionalized nanoparticles
Communications Materials
author_facet Hironobu Machida
Takeshi Sugahara
Izumi Hirasawa
author_sort Hironobu Machida
title The moment of initial crystallization captured on functionalized nanoparticles
title_short The moment of initial crystallization captured on functionalized nanoparticles
title_full The moment of initial crystallization captured on functionalized nanoparticles
title_fullStr The moment of initial crystallization captured on functionalized nanoparticles
title_full_unstemmed The moment of initial crystallization captured on functionalized nanoparticles
title_sort moment of initial crystallization captured on functionalized nanoparticles
publisher Nature Publishing Group
series Communications Materials
issn 2662-4443
publishDate 2021-06-01
description Understanding the mechanism of supercooling suppression by crystallization seeds is important for designing semiclathrate hydrates for latent heat storage materials. Here, we show that 10-30 nm cluster formation around silver nanoparticles promotes crystallization of supercooled aqueous solutions.
url https://doi.org/10.1038/s43246-021-00171-w
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AT hironobumachida momentofinitialcrystallizationcapturedonfunctionalizednanoparticles
AT takeshisugahara momentofinitialcrystallizationcapturedonfunctionalizednanoparticles
AT izumihirasawa momentofinitialcrystallizationcapturedonfunctionalizednanoparticles
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