Preparation of Advanced Carbon Anode Materials from Mesocarbon Microbeads for Use in High C-Rate Lithium Ion Batteries

Mesophase soft carbon (MSC) and mesophase graphite (SMG), for use in comparative studies of high C-rate Lithium Ion Battery (LIB) anodes, were made by heating mesocarbon microbeads (MCMB) at 1300 °C and 3000 °C; respectively. The crystalline structures and morphologies of the MSC, SMG, and commercia...

Full description

Bibliographic Details
Main Authors: Ming-Dar Fang, Tsung-Han Ho, Jui-Pin Yen, Yu-Run Lin, Jin-Long Hong, She-Huang Wu, Jiin-Jiang Jow
Format: Article
Language:English
Published: MDPI AG 2015-06-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/8/6/3550
Description
Summary:Mesophase soft carbon (MSC) and mesophase graphite (SMG), for use in comparative studies of high C-rate Lithium Ion Battery (LIB) anodes, were made by heating mesocarbon microbeads (MCMB) at 1300 °C and 3000 °C; respectively. The crystalline structures and morphologies of the MSC, SMG, and commercial hard carbon (HC) were investigated by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and Raman spectroscopy. Additionally, their electrochemical properties, when used as anode materials in LIBs, were also investigated. The results show that MSC has a superior charging rate capability compared to SMG and HC. This is attributed to MSC having a more extensive interlayer spacing than SMG, and a greater number of favorably-oriented pathways when compared to HC.
ISSN:1996-1944