Syntheses, Crystal Structures, Antimicrobial Activity and Thermal Behavior of Copper(II) Complexes Derived from 1-Naphthylacetic Acid and Diamines

Syntheses, Crystal Structures, Antimicrobial Activity and Thermal Behavior of Copper(II) Complexes Derived from 1-Naphthylacetic Acid and Diamines

Two copper(II) complexes, [CuL2(EA)] (1) and [Cu2L4(PA)2]·2H2O (2·2H2O), where L is 1-naphthylacetate, EA is N,N-diethylethane-1,2-diamine, PA is propane-1,3-diamine, have been prepared and characterized. Structures of the complexes have been characterized by single-cyrstal X-ray diffraction. Comple...

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Bibliographic Details
Main Authors: Ling-Wei Xue, Chen Chen, Gan-Qing Zhao, Wei-Chun Yang
Format: Article
Language:English
Published: Slovenian Chemical Society 2020-03-01
Series:Acta Chimica Slovenica
Subjects:
copper complex
crystal structure
hydrogen bonding
antimicrobial activity
thermal property
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/5327
Description
Summary:Two copper(II) complexes, [CuL2(EA)] (1) and [Cu2L4(PA)2]·2H2O (2·2H2O), where L is 1-naphthylacetate, EA is N,N-diethylethane-1,2-diamine, PA is propane-1,3-diamine, have been prepared and characterized. Structures of the complexes have been characterized by single-cyrstal X-ray diffraction. Complex 1 is a mononuclear copper(II) compound, with the Cu atoms coordinated in square planar geometry. Complex 2·2H2O is a centrosymmetric dinuclear copper(II) compound, with the Cu atoms coordinated in square pyramidal geometry. Single crystals of the complexes are stabilized by hydrogen bonds. The effects of the compounds on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans, as well as thermal behavior of the complexes were studied.
ISSN:1318-0207
1580-3155

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