Effect of octadecylamine concentration on adsorption on carbon steel surface

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulat...

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Main Authors: Canshuai Liu, Genxian Lin, Yun Sun, Jundong Lu, Jun Fang, Chun Yu, Lisheng Chi, Ke Sun
Format: Article
Language:English
Published: Elsevier 2020-10-01
Series:Nuclear Engineering and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1738573320301066
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spelling doaj-ee233e3fd8324414ba4cb2675571168c2020-11-25T03:42:13ZengElsevierNuclear Engineering and Technology1738-57332020-10-01521023942401Effect of octadecylamine concentration on adsorption on carbon steel surfaceCanshuai Liu0Genxian Lin1Yun Sun2Jundong Lu3Jun Fang4Chun Yu5Lisheng Chi6Ke Sun7Suzhou Nuclear Power Research Institute Co., Ltd., Jiangsu, Suzhou, 215008, China; Fujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, ChinaSuzhou Nuclear Power Research Institute Co., Ltd., Jiangsu, Suzhou, 215008, ChinaSuzhou Nuclear Power Research Institute Co., Ltd., Jiangsu, Suzhou, 215008, ChinaSuzhou Nuclear Power Research Institute Co., Ltd., Jiangsu, Suzhou, 215008, ChinaSuzhou Nuclear Power Research Institute Co., Ltd., Jiangsu, Suzhou, 215008, ChinaFujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, ChinaFujian Key Laboratory of Fuel and Materials in Clean Nuclear Energy System, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China; Corresponding author.Daya Bay Nuclear Power Operation and Management Co., Ltd, Guangdong, Shenzhen, 518124, ChinaOctadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.http://www.sciencedirect.com/science/article/pii/S1738573320301066OctadecylamineConcentrationAdsorption mechanismThickness
collection DOAJ
language English
format Article
sources DOAJ
author Canshuai Liu
Genxian Lin
Yun Sun
Jundong Lu
Jun Fang
Chun Yu
Lisheng Chi
Ke Sun
spellingShingle Canshuai Liu
Genxian Lin
Yun Sun
Jundong Lu
Jun Fang
Chun Yu
Lisheng Chi
Ke Sun
Effect of octadecylamine concentration on adsorption on carbon steel surface
Nuclear Engineering and Technology
Octadecylamine
Concentration
Adsorption mechanism
Thickness
author_facet Canshuai Liu
Genxian Lin
Yun Sun
Jundong Lu
Jun Fang
Chun Yu
Lisheng Chi
Ke Sun
author_sort Canshuai Liu
title Effect of octadecylamine concentration on adsorption on carbon steel surface
title_short Effect of octadecylamine concentration on adsorption on carbon steel surface
title_full Effect of octadecylamine concentration on adsorption on carbon steel surface
title_fullStr Effect of octadecylamine concentration on adsorption on carbon steel surface
title_full_unstemmed Effect of octadecylamine concentration on adsorption on carbon steel surface
title_sort effect of octadecylamine concentration on adsorption on carbon steel surface
publisher Elsevier
series Nuclear Engineering and Technology
issn 1738-5733
publishDate 2020-10-01
description Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.
topic Octadecylamine
Concentration
Adsorption mechanism
Thickness
url http://www.sciencedirect.com/science/article/pii/S1738573320301066
work_keys_str_mv AT canshuailiu effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT genxianlin effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT yunsun effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT jundonglu effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT junfang effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT chunyu effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT lishengchi effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
AT kesun effectofoctadecylamineconcentrationonadsorptiononcarbonsteelsurface
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