Electrochemical Response of Platinum Ultrathin Layer Formed by Pulsed Laser Deposition

• Main Authors: Takeshi Ito, Satoru Kaneko, Masayuki Kunimatsu, Yasuo Hirabayashi, Masayasu Soga, Koji Suzuki
• Format: Article
• Language: English
• Published: Hindawi Limited 2011-01-01
• Series: International Journal of Electrochemistry
• Online Access: http://dx.doi.org/10.4061/2011/463281

Ultrathin layer of platinum (ULPt) was deposited on glassy carbon (GC) substrate by using pulsed laser deposition (PLD) method, and electrochemical properties of the ULPt were discussed. The deposition was simply performed at room temperature with short deposition time. Atomic force microscopy and scanning electron microscopy images showed the flat surface of the ULPt. X-ray photoelectron spectroscopy (XPS) characterized the ULPt in the Pt(0) state, and biding energy of ULPt was positively shifted. These results indicated that nanostructure of Pt thin layer was formed. The electrochemical activity of the prepared ULPt on GC substrate was superior to a bulk Pt electrode regarding the potential and the magnitude of current on oxidizing hydrogen peroxide. This fast and easily prepared low-cost electrode had the potential to replace a conventional bulk metal electrode.