Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II)
In the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular inte...
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International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810052530 |
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doaj-edac008f60d548a8950c1ef5b4f581862020-11-24T23:55:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m117m11810.1107/S1600536810052530Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II)Shou-Ling HuangKuang-Hway YihHsiao-Fen WangGene-Hsiang LeeIn the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H...O, C—H...Cl, C—H...π(arene) hydrogen bonds and CO...π(arene) interactions [O...centroid distances = 3.485 (4) and 3.722 (3) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536810052530 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Shou-Ling Huang Kuang-Hway Yih Hsiao-Fen Wang Gene-Hsiang Lee |
| spellingShingle |
Shou-Ling Huang Kuang-Hway Yih Hsiao-Fen Wang Gene-Hsiang Lee Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) Acta Crystallographica Section E |
| author_facet |
Shou-Ling Huang Kuang-Hway Yih Hsiao-Fen Wang Gene-Hsiang Lee |
| author_sort |
Shou-Ling Huang |
| title |
Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_short |
Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_full |
Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_fullStr |
Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_full_unstemmed |
Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II) |
| title_sort |
dicarbonylchlorido(phenoxythiocarbonyl-κ2c,s)bis(triphenylphosphane-κp)molybdenum(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-01-01 |
| description |
In the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H...O, C—H...Cl, C—H...π(arene) hydrogen bonds and CO...π(arene) interactions [O...centroid distances = 3.485 (4) and 3.722 (3) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810052530 |
| work_keys_str_mv |
AT shoulinghuang dicarbonylchloridophenoxythiocarbonylamp9542csbistriphenylphosphaneamp954pmolybdenumii AT kuanghwayyih dicarbonylchloridophenoxythiocarbonylamp9542csbistriphenylphosphaneamp954pmolybdenumii AT hsiaofenwang dicarbonylchloridophenoxythiocarbonylamp9542csbistriphenylphosphaneamp954pmolybdenumii AT genehsianglee dicarbonylchloridophenoxythiocarbonylamp9542csbistriphenylphosphaneamp954pmolybdenumii |
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1725462522005291008 |