Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II)

• Main Authors: Shou-Ling Huang, Kuang-Hway Yih, Hsiao-Fen Wang, Gene-Hsiang Lee
• Format: Article
• Language: English
• Published: International Union of Crystallography 2011-01-01
• Series: Acta Crystallographica Section E
• Online Access: http://scripts.iucr.org/cgi-bin/paper?S1600536810052530
• ISSN: 1600-5368

In the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H...O, C—H...Cl, C—H...π(arene) hydrogen bonds and CO...π(arene) interactions [O...centroid distances = 3.485 (4) and 3.722 (3) Å].