[μ-2-(4-Hydroxyphenyl)acetato]-κ3O:O,O′;κ3O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]holmium(III)} monohydrate

[μ-2-(4-Hydroxyphenyl)acetato]-κ3O:O,O′;κ3O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]holmium(III)} monohydrate

In the title dinuclear complex, [Ho2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, each of the two independent HoIII ions is coordinated by eight O atoms from four 4-hydroxyphenylacetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine (bipy) ligand in a distort...

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Bibliographic Details
Main Authors: Jia-Lu Liu, Jian-Feng Liu, Guo-Liang Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811001115
Description
Summary:In the title dinuclear complex, [Ho2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, each of the two independent HoIII ions is coordinated by eight O atoms from four 4-hydroxyphenylacetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine (bipy) ligand in a distorted tricapped trigonal–prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O—H...O and O—H...N hydrogen bonds link the molecules into a three-dimensional network.
ISSN:1600-5368

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