Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium]
The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom....
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812045928 |
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doaj-ed7117dd77ca4034bad606f33b2d6eee2020-11-24T21:55:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1471m147110.1107/S1600536812045928Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium]Sadif A. ShirvanSara Haydari DezfuliFereydoon KhazaliManouchehr AghajeriAli BorsalaniThe title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom. In the crystal, C—H...Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812045928 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Sadif A. Shirvan Sara Haydari Dezfuli Fereydoon Khazali Manouchehr Aghajeri Ali Borsalani |
| spellingShingle |
Sadif A. Shirvan Sara Haydari Dezfuli Fereydoon Khazali Manouchehr Aghajeri Ali Borsalani Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] Acta Crystallographica Section E |
| author_facet |
Sadif A. Shirvan Sara Haydari Dezfuli Fereydoon Khazali Manouchehr Aghajeri Ali Borsalani |
| author_sort |
Sadif A. Shirvan |
| title |
Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] |
| title_short |
Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] |
| title_full |
Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] |
| title_fullStr |
Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] |
| title_full_unstemmed |
Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium] |
| title_sort |
di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2n,n′)cadmium] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-12-01 |
| description |
The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom. In the crystal, C—H...Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supramolecular structure. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812045928 |
| work_keys_str_mv |
AT sadifashirvan diamp956bromidobisbromido47diphenyl110phenanthrolineamp9542nnamp8242cadmium AT sarahaydaridezfuli diamp956bromidobisbromido47diphenyl110phenanthrolineamp9542nnamp8242cadmium AT fereydoonkhazali diamp956bromidobisbromido47diphenyl110phenanthrolineamp9542nnamp8242cadmium AT manouchehraghajeri diamp956bromidobisbromido47diphenyl110phenanthrolineamp9542nnamp8242cadmium AT aliborsalani diamp956bromidobisbromido47diphenyl110phenanthrolineamp9542nnamp8242cadmium |
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1725860828289171456 |