Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium]

Di-μ-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cadmium]

The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom....

Full description

Bibliographic Details
Main Authors: Sadif A. Shirvan, Sara Haydari Dezfuli, Fereydoon Khazali, Manouchehr Aghajeri, Ali Borsalani
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812045928
Description
Summary:The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom. In the crystal, C—H...Br hydrogen bonds and π–π contacts between the pyridine and phenyl rings [centroid–centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supramolecular structure.
ISSN:1600-5368

Similar Items