2,2′-{1,1′-[Pentane-1,5-diylbis(oxynitrilo)]diethylidyne}di-1-naphthol

The title compound, C29H30N2O4, adopts a distorted Z configuration with respect to the oxime group, which is almost coplanar with the adjacent naphthalene ring [dihedral angle = 4.11 (2)°]. There is one half-molecule in the asymmetric unit, with a crystallographic twofold...

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Bibliographic Details
Main Authors: Yin-Xia Sun, Jian-Chao Wu, Wen-Kui Dong, Shang-sheng Gong, Jun-Feng Tong
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809016584
Description
Summary:The title compound, C29H30N2O4, adopts a distorted Z configuration with respect to the oxime group, which is almost coplanar with the adjacent naphthalene ring [dihedral angle = 4.11 (2)°]. There is one half-molecule in the asymmetric unit, with a crystallographic twofold rotation axis passing through the central C atom of the –CH=N—O-(CH)5—O—N=CH– bridge. Within the molecule, the dihedral angle formed by the two naphthalene rings is 79.08 (3)°, and there are two intramolecular O—H...N hydrogen bonds.
ISSN:1600-5368