Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose

The inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflect...

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Main Authors: H. D. Juneja, Manisha Joshi, N. T. KhatiI
Format: Article
Language:English
Published: Hindawi Limited 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/369492
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spelling doaj-ec152fd87dae4ca7a6b0fb9291b69ec72020-11-24T23:01:08ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102011-01-01841993199910.1155/2011/369492Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl CelluloseH. D. Juneja0Manisha Joshi1N. T. KhatiI2Department of Chemistry, R T M Nagpur University, Nagpur-440033, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur-440019, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur-440019, IndiaThe inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflectance spectra and magnetic moment. On the basis of these studies, the composition of the polymeric unit was found to be [M(II)L]n, [Mʼ(II)L.2H2 O]n, {[Mˮ(II)L.2H2O]n H2O}, where M= Zn(II), Mʼ = Mn(II), Ni(II) and Cu(II) and Mˮ = Co(II), L = SCMC ligand. On the basis of instrumental techniques, it has been found that the [Zn(II)(SCMC)]n inorganic polymer has tetrahedral geometry, whereas {[Cu(II)(SCMC)].2H2O}n has square planar geometry and [Mn(II)(SCMC).2H2O]n, {[Co(II)(SCMC).2H2O)].H2O}n and [Ni(II) (SCMC).2H2O]n have octahedral geometry. The decomposition temperatures of the inorganic polymers have been determined by TGA. The TGA reveal that the Mn(II) polymer of SCMC is highly thermally stable than rest of the polymers and these polymers can be used as thermal resisting materials.http://dx.doi.org/10.1155/2011/369492
collection DOAJ
language English
format Article
sources DOAJ
author H. D. Juneja
Manisha Joshi
N. T. KhatiI
spellingShingle H. D. Juneja
Manisha Joshi
N. T. KhatiI
Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
E-Journal of Chemistry
author_facet H. D. Juneja
Manisha Joshi
N. T. KhatiI
author_sort H. D. Juneja
title Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
title_short Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
title_full Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
title_fullStr Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
title_full_unstemmed Synthesis and Structural Studies of Some Inorganic Polymers of Succinoyl Carboxymethyl Cellulose
title_sort synthesis and structural studies of some inorganic polymers of succinoyl carboxymethyl cellulose
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2011-01-01
description The inorganic polymers containing transition metals such as Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) were synthesized by using succinoyl carboxymethyl cellulose (SCMC) in aqueous media. The newly synthesized polymers were characterized by elemental analysis, IR spectroscopy, TG analysis, UV reflectance spectra and magnetic moment. On the basis of these studies, the composition of the polymeric unit was found to be [M(II)L]n, [Mʼ(II)L.2H2 O]n, {[Mˮ(II)L.2H2O]n H2O}, where M= Zn(II), Mʼ = Mn(II), Ni(II) and Cu(II) and Mˮ = Co(II), L = SCMC ligand. On the basis of instrumental techniques, it has been found that the [Zn(II)(SCMC)]n inorganic polymer has tetrahedral geometry, whereas {[Cu(II)(SCMC)].2H2O}n has square planar geometry and [Mn(II)(SCMC).2H2O]n, {[Co(II)(SCMC).2H2O)].H2O}n and [Ni(II) (SCMC).2H2O]n have octahedral geometry. The decomposition temperatures of the inorganic polymers have been determined by TGA. The TGA reveal that the Mn(II) polymer of SCMC is highly thermally stable than rest of the polymers and these polymers can be used as thermal resisting materials.
url http://dx.doi.org/10.1155/2011/369492
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AT manishajoshi synthesisandstructuralstudiesofsomeinorganicpolymersofsuccinoylcarboxymethylcellulose
AT ntkhatii synthesisandstructuralstudiesofsomeinorganicpolymersofsuccinoylcarboxymethylcellulose
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