Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency
Planar perovskite solar cells were fabricated on F-doped SnO<sub>2</sub> (FTO) coated glass substrates, with 4,4’-((1E,1’E)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) (bTAThDaz) as hole transport...
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MDPI AG
2020-05-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/13/11/2440 |
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doaj-eb8c4c74cb854719ae63dedf62a974f5 |
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| record_format |
Article |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Krzysztof Artur Bogdanowicz Beata Jewłoszewicz Agnieszka Iwan Karolina Dysz Wojciech Przybyl Adam Januszko Monika Marzec Kacper Cichy Konrad Świerczek Ladislav Kavan Markéta Zukalová Vojtech Nadazdy Riyas Subair Eva Majkova Matej Micusik Maria Omastova Mehmer Derya Özeren Katalin Kamarás Do Yeon Heo Soo Young Kim |
| spellingShingle |
Krzysztof Artur Bogdanowicz Beata Jewłoszewicz Agnieszka Iwan Karolina Dysz Wojciech Przybyl Adam Januszko Monika Marzec Kacper Cichy Konrad Świerczek Ladislav Kavan Markéta Zukalová Vojtech Nadazdy Riyas Subair Eva Majkova Matej Micusik Maria Omastova Mehmer Derya Özeren Katalin Kamarás Do Yeon Heo Soo Young Kim Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency Materials imines azomethines perovskite solar cells HTM electrochemical impedance spectroscopy thermographic camera |
| author_facet |
Krzysztof Artur Bogdanowicz Beata Jewłoszewicz Agnieszka Iwan Karolina Dysz Wojciech Przybyl Adam Januszko Monika Marzec Kacper Cichy Konrad Świerczek Ladislav Kavan Markéta Zukalová Vojtech Nadazdy Riyas Subair Eva Majkova Matej Micusik Maria Omastova Mehmer Derya Özeren Katalin Kamarás Do Yeon Heo Soo Young Kim |
| author_sort |
Krzysztof Artur Bogdanowicz |
| title |
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency |
| title_short |
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency |
| title_full |
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency |
| title_fullStr |
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency |
| title_full_unstemmed |
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency |
| title_sort |
selected electrochemical properties of 4,4’-((1e,1’e)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>n</i>,<i>n</i>-di-p-tolylaniline) towards perovskite solar cells with 14.4% efficiency |
| publisher |
MDPI AG |
| series |
Materials |
| issn |
1996-1944 |
| publishDate |
2020-05-01 |
| description |
Planar perovskite solar cells were fabricated on F-doped SnO<sub>2</sub> (FTO) coated glass substrates, with 4,4’-((1E,1’E)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) (bTAThDaz) as hole transport material. This imine was synthesized in one step reaction, starting from commercially available and relatively inexpensive reagents. Electrochemical, optical, electrical, thermal and structural studies including thermal images and current-voltage measurements of the full solar cell devices characterize the imine in details. HOMO-LUMO of bTAThDaz were investigated by cyclic voltammetry (CV) and energy-resolved electrochemical impedance spectroscopy (ER-EIS) and were found at −5.19 eV and −2.52 eV (CV) and at −5.5 eV and −2.3 eV (ER-EIS). The imine exhibited 5% weight loss at 156 °C. The electrical behavior and photovoltaic performance of the perovskite solar cell was examined for FTO/TiO<sub>2</sub>/perovskite/bTAThDaz/Ag device architecture. Constructed devices exhibited good time and air stability together with quite small effect of hysteresis. The observed solar conversion efficiency was 14.4%. |
| topic |
imines azomethines perovskite solar cells HTM electrochemical impedance spectroscopy thermographic camera |
| url |
https://www.mdpi.com/1996-1944/13/11/2440 |
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doaj-eb8c4c74cb854719ae63dedf62a974f52020-11-25T02:48:50ZengMDPI AGMaterials1996-19442020-05-01132440244010.3390/ma13112440Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% EfficiencyKrzysztof Artur Bogdanowicz0Beata Jewłoszewicz1Agnieszka Iwan2Karolina Dysz3Wojciech Przybyl4Adam Januszko5Monika Marzec6Kacper Cichy7Konrad Świerczek8Ladislav Kavan9Markéta Zukalová10Vojtech Nadazdy11Riyas Subair12Eva Majkova13Matej Micusik14Maria Omastova15Mehmer Derya Özeren16Katalin Kamarás17Do Yeon Heo18Soo Young Kim19Military Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandMilitary Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandMilitary Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandMilitary Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandMilitary Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandMilitary Institute of Engineer Technology, Obornicka 136 Str., 50-961 Wroclaw, PolandInstitute of Physics, Jagiellonian University, 11, 30-348 Krakow, PolandFaculty of Energy and Fuels, AGH University of Science and Technology. A. Mickiewicza 30, 30-059 Krakow, PolandFaculty of Energy and Fuels, AGH University of Science and Technology. A. Mickiewicza 30, 30-059 Krakow, PolandDepartment of Electrochemical Materials, J. Heyrovsky Institute of Physical Chemistry, Czech Academic Science, Dolejskova 3, 18223 Prague, Czech RepublicDepartment of Electrochemical Materials, J. Heyrovsky Institute of Physical Chemistry, Czech Academic Science, Dolejskova 3, 18223 Prague, Czech RepublicInstitute of Physics, Slovak Academy of Science, Dubravska cesta, 9, 845 11 Bratislava, SlovakiaInstitute of Physics, Slovak Academy of Science, Dubravska cesta, 9, 845 11 Bratislava, SlovakiaInstitute of Physics, Slovak Academy of Science, Dubravska cesta, 9, 845 11 Bratislava, SlovakiaPolymer Institute, Slovak Academy of Science, Dubravska cesta, 9, 845 41 Bratislava, SlovakiaPolymer Institute, Slovak Academy of Science, Dubravska cesta, 9, 845 41 Bratislava, SlovakiaInstitute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, Konkoly Thege u. 29-33, 1121 Budapest, HungaryInstitute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, Konkoly Thege u. 29-33, 1121 Budapest, HungaryDepartment of Materials Science and Engineering, Korea University 145, Anam-ro Seongbuk-gu, Seoul 02841, KoreaDepartment of Materials Science and Engineering, Korea University 145, Anam-ro Seongbuk-gu, Seoul 02841, KoreaPlanar perovskite solar cells were fabricated on F-doped SnO<sub>2</sub> (FTO) coated glass substrates, with 4,4’-((1E,1’E)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(<i>N</i>,<i>N</i>-di-p-tolylaniline) (bTAThDaz) as hole transport material. This imine was synthesized in one step reaction, starting from commercially available and relatively inexpensive reagents. Electrochemical, optical, electrical, thermal and structural studies including thermal images and current-voltage measurements of the full solar cell devices characterize the imine in details. HOMO-LUMO of bTAThDaz were investigated by cyclic voltammetry (CV) and energy-resolved electrochemical impedance spectroscopy (ER-EIS) and were found at −5.19 eV and −2.52 eV (CV) and at −5.5 eV and −2.3 eV (ER-EIS). The imine exhibited 5% weight loss at 156 °C. The electrical behavior and photovoltaic performance of the perovskite solar cell was examined for FTO/TiO<sub>2</sub>/perovskite/bTAThDaz/Ag device architecture. Constructed devices exhibited good time and air stability together with quite small effect of hysteresis. The observed solar conversion efficiency was 14.4%.https://www.mdpi.com/1996-1944/13/11/2440iminesazomethinesperovskite solar cellsHTMelectrochemical impedance spectroscopythermographic camera |