Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System
In this paper, nano-montmorillonite (nano-MMT) was introduced into the microbial mineralization system of strontium carbonate (SrCO<sub>3</sub>). By changing the nano-MMT concentration and the mineralization time, the mechanism of mineralization was studied. SrCO<sub>3</sub>...
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doaj-eb6c2e64a41e48bda46a98b9ef9f66ba2020-11-25T00:52:59ZengMDPI AGMaterials1996-19442019-04-01129139210.3390/ma12091392ma12091392Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization SystemKui Zheng0Tao Chen1Jian Zhang2Xiuquan Tian3Huilin Ge4Tiantao Qiao5Jia Lei6Xianyan Li7Tao Duan8Wenkun Zhu9Analytical and Testing Center, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Environmentally Friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, ChinaIn this paper, nano-montmorillonite (nano-MMT) was introduced into the microbial mineralization system of strontium carbonate (SrCO<sub>3</sub>). By changing the nano-MMT concentration and the mineralization time, the mechanism of mineralization was studied. SrCO<sub>3</sub> superstructures with complex forms were acquired in the presence of nano-MMT as a crystal growth regulator. At low concentrations of nano-MMT, a cross-shaped SrCO<sub>3</sub> superstructure was obtained. As the concentration increased, flower-like SrCO<sub>3</sub> crystals formed via the dissolution and recrystallization processes. An emerging self-assembly process and crystal polymerization mechanism have been proposed by forming complex flower-like SrCO<sub>3</sub> superstructures in high concentrations of nano-MMT. The above research indicated that unique bionic synthesis strategies in microbial systems could not only provide a useful route for the production of inorganic or inorganic/organic composites with a novel morphology and unique structure but also provide new ideas for the treatment of radionuclides.https://www.mdpi.com/1996-1944/12/9/1392biomineralizationmicroorganismstrontium carbonatenano-montmorillonite |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kui Zheng Tao Chen Jian Zhang Xiuquan Tian Huilin Ge Tiantao Qiao Jia Lei Xianyan Li Tao Duan Wenkun Zhu |
spellingShingle |
Kui Zheng Tao Chen Jian Zhang Xiuquan Tian Huilin Ge Tiantao Qiao Jia Lei Xianyan Li Tao Duan Wenkun Zhu Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System Materials biomineralization microorganism strontium carbonate nano-montmorillonite |
author_facet |
Kui Zheng Tao Chen Jian Zhang Xiuquan Tian Huilin Ge Tiantao Qiao Jia Lei Xianyan Li Tao Duan Wenkun Zhu |
author_sort |
Kui Zheng |
title |
Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System |
title_short |
Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System |
title_full |
Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System |
title_fullStr |
Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System |
title_full_unstemmed |
Nano-Montmorillonite Regulated Crystallization of Hierarchical Strontium Carbonate in a Microbial Mineralization System |
title_sort |
nano-montmorillonite regulated crystallization of hierarchical strontium carbonate in a microbial mineralization system |
publisher |
MDPI AG |
series |
Materials |
issn |
1996-1944 |
publishDate |
2019-04-01 |
description |
In this paper, nano-montmorillonite (nano-MMT) was introduced into the microbial mineralization system of strontium carbonate (SrCO<sub>3</sub>). By changing the nano-MMT concentration and the mineralization time, the mechanism of mineralization was studied. SrCO<sub>3</sub> superstructures with complex forms were acquired in the presence of nano-MMT as a crystal growth regulator. At low concentrations of nano-MMT, a cross-shaped SrCO<sub>3</sub> superstructure was obtained. As the concentration increased, flower-like SrCO<sub>3</sub> crystals formed via the dissolution and recrystallization processes. An emerging self-assembly process and crystal polymerization mechanism have been proposed by forming complex flower-like SrCO<sub>3</sub> superstructures in high concentrations of nano-MMT. The above research indicated that unique bionic synthesis strategies in microbial systems could not only provide a useful route for the production of inorganic or inorganic/organic composites with a novel morphology and unique structure but also provide new ideas for the treatment of radionuclides. |
topic |
biomineralization microorganism strontium carbonate nano-montmorillonite |
url |
https://www.mdpi.com/1996-1944/12/9/1392 |
work_keys_str_mv |
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1725239854534492160 |