The Effect of Degradation of Soda Lignin Using Pd/SO₄²⁻/ZrO₂ as a Catalyst: Improved Reactivity and Antioxidant Activity

• Main Authors: Shengming Zhang, Guizhen Fang, Haitao Chen, Qian Lang
• Format: Article
• Language: English
• Published: MDPI AG 2019-07-01
• Series: Polymers
• Subjects: soda lignin; Pd/SO₄²⁻/ZrO₂ catalyst; degradation; antioxidant activity; reactivity
• Online Access: https://www.mdpi.com/2073-4360/11/7/1218

To the value-added application of the soda lignin by improving its reactivity and antioxidant activity, a self-made Pd/SO₄²^−/ZrO₂ catalyst was used to catalyze the degradation reaction of soda lignin. The catalyst was loaded with the palladium of 1.47 wt.% while retaining the super acidity of SO₄²^−/ZrO₂. The reaction condition was determined as follows: the dioxane-water solution was selected as the reaction solution, the addition amount of the catalyst was 5 wt.% of the soda lignin, the system was heated at 100 °C for 4 h under a hydrogen pressure of 3 MPa. The reactivity of the catalyzed-soda lignin compared to the soda lignin before the reaction was significantly improved: the values of phenolic hydroxyl groups and total hydroxyl groups were increased by 35.3% and 97.1%, respectively, and the value of methoxy groups was decreased by 13%. Approximately 63.3% of the β-O-4 bonds were cleaved, which resulted in a reduction of the weight average molecular weight from 8200 g·mol^−1 to 4900 g·mol^−1. At the same time, the EC₅₀ values of the catalyzed-soda lignin on DPPH (1,1-diphenyl-2-picrylhydrazyl) and ABTS⁺ (2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate) radicals scavenging were decreased by 20.6% and 32.6%, respectively, and the reducing power of catalyzed-soda lignin at the absorption value of 0.5 was increased by 10.5%. The Pd/SO₄²^−/ZrO₂ catalyst works by breaking the β-O-4 linkages and degrading the methoxy groups. The catalyzed-soda lignin exhibits the possibility of being used as the antioxidants, grafting precursors, adhesive additives, and raw materials for lignin/polymer composites.