3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate

3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate

In the structure of the title compound, C26H22N4O3·2C3H7NO, one of the DMF solvent molecules is disordered over two sets of positions in a 0.5:0.5 ratio. In the 1,1′-[2,2′-oxybis(2,1-phenylene)]bis(3-phenylurea) molecule, the two diphenylurea segments are linked via an e...

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Main Authors: Yiannis C. Charalambides, Stephen C. Moratti, Jim Simpson
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807066548
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spelling doaj-eb1a966b0a2b4cabbc8dcf6c28741b342020-11-25T00:49:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o305o30610.1107/S16005368070665483,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvateYiannis C. CharalambidesStephen C. MorattiJim SimpsonIn the structure of the title compound, C26H22N4O3·2C3H7NO, one of the DMF solvent molecules is disordered over two sets of positions in a 0.5:0.5 ratio. In the 1,1′-[2,2′-oxybis(2,1-phenylene)]bis(3-phenylurea) molecule, the two diphenylurea segments are linked via an ether O atom and are inclined at an angle of 53.80 (4)° to one another. In the crystal structure, classical N—H...O hydrogen bonds link each molecule to two DMF solvent molecules and these aggregates form columns down a through C—H...π interactions. Additional C—H...O interactions link the main molecule and the solvent molecules, forming columns of independent zigzag chains along b.http://scripts.iucr.org/cgi-bin/paper?S1600536807066548
collection DOAJ
language English
format Article
sources DOAJ
author Yiannis C. Charalambides
Stephen C. Moratti
Jim Simpson
spellingShingle Yiannis C. Charalambides
Stephen C. Moratti
Jim Simpson
3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
Acta Crystallographica Section E
author_facet Yiannis C. Charalambides
Stephen C. Moratti
Jim Simpson
author_sort Yiannis C. Charalambides
title 3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
title_short 3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
title_full 3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
title_fullStr 3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
title_full_unstemmed 3,3′-Diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea N,N-dimethylformamide disolvate
title_sort 3,3′-diphenyl-1,1′-[2,2′-oxybis(2,1-phenylene)]diurea n,n-dimethylformamide disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the structure of the title compound, C26H22N4O3·2C3H7NO, one of the DMF solvent molecules is disordered over two sets of positions in a 0.5:0.5 ratio. In the 1,1′-[2,2′-oxybis(2,1-phenylene)]bis(3-phenylurea) molecule, the two diphenylurea segments are linked via an ether O atom and are inclined at an angle of 53.80 (4)° to one another. In the crystal structure, classical N—H...O hydrogen bonds link each molecule to two DMF solvent molecules and these aggregates form columns down a through C—H...π interactions. Additional C—H...O interactions link the main molecule and the solvent molecules, forming columns of independent zigzag chains along b.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807066548
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AT stephencmoratti 338242diphenyl118242228242oxybis21phenylenediureanndimethylformamidedisolvate
AT jimsimpson 338242diphenyl118242228242oxybis21phenylenediureanndimethylformamidedisolvate
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