μ-1,4-Bis(pyridin-4-ylmethyl)piperazine-κ2N:N′-bis[aquabis(3-bromo-5-carboxybenzoato-κO1)copper(II)]

μ-1,4-Bis(pyridin-4-ylmethyl)piperazine-κ2N:N′-bis[aquabis(3-bromo-5-carboxybenzoato-κO1)copper(II)]

In the title compound, [Cu2(C8H4BrO4)4(C16H20N4)(H2O)2], slightly distorted square-planar-coordinated CuII ions are bound by one aqua ligand and two monodentate 3-bromo-5-carboxybenzoate anions, and linked into a centrosymmetric dinuclear molecule by a bridging 1,4-bis(pyridin-4-ylmethyl)piperazine...

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Bibliographic Details
Main Authors: Jodi L. Meyer, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812000979
Description
Summary:In the title compound, [Cu2(C8H4BrO4)4(C16H20N4)(H2O)2], slightly distorted square-planar-coordinated CuII ions are bound by one aqua ligand and two monodentate 3-bromo-5-carboxybenzoate anions, and linked into a centrosymmetric dinuclear molecule by a bridging 1,4-bis(pyridin-4-ylmethyl)piperazine (4-bpmp) ligand. In the crystal, molecules are connected into a supramolecular two-dimensional network parallel to (131) via O—H...O hydrogen bonds involving the aqua ligands and 3-bromo-5-carboxybenzoate carboxylate groups.
ISSN:1600-5368

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