Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition
Tuning the architecture of multilayer nanostructures by exploiting the properties of their constituents is a versatile way to develop multifunctional films. Herein, we report a bottom-up approach for the fabrication of highly ordered hybrid films consisting of dimethyldioctadecylammonium (DODA), iro...
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MDPI AG
2020-01-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/13/1/216 |
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doaj-eb1174a60e074b1c969e885d170b624a2020-11-25T01:46:21ZengMDPI AGMaterials1996-19442020-01-0113121610.3390/ma13010216ma13010216Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer DepositionJiquan Wu0Georgia Potsi1Regis Y. N. Gengler2Dimitrios Gournis3Petra Rudolf4Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsDepartment of Materials Science & Engineering, University of Ioannina, GR-45110 Ioannina, GreeceZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsTuning the architecture of multilayer nanostructures by exploiting the properties of their constituents is a versatile way to develop multifunctional films. Herein, we report a bottom-up approach for the fabrication of highly ordered hybrid films consisting of dimethyldioctadecylammonium (DODA), iron decorated polyhedral oligomeric silsesquioxanes (POSS), and montmorillonite clay platelets. Clay platelets provided the template where Fe/POSS moieties were grafted by the use of the surfactant. Driven by the iron ions present, DODA adopted a staggered arrangement, which is essential to realize the controllable layer-by-layer growth of the film. The elemental composition of the film was studied by X-ray photoelectron spectroscopy and X-ray reflectivity confirmed the existence of smooth interfaces between the different layers.https://www.mdpi.com/1996-1944/13/1/216langmuir–schaeferpolyhedral oligomeric silsesquioxaneslayered thin filmsmontmorillonite films |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Jiquan Wu Georgia Potsi Regis Y. N. Gengler Dimitrios Gournis Petra Rudolf |
| spellingShingle |
Jiquan Wu Georgia Potsi Regis Y. N. Gengler Dimitrios Gournis Petra Rudolf Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition Materials langmuir–schaefer polyhedral oligomeric silsesquioxanes layered thin films montmorillonite films |
| author_facet |
Jiquan Wu Georgia Potsi Regis Y. N. Gengler Dimitrios Gournis Petra Rudolf |
| author_sort |
Jiquan Wu |
| title |
Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition |
| title_short |
Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition |
| title_full |
Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition |
| title_fullStr |
Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition |
| title_full_unstemmed |
Insertion of Iron Decorated Organic–Inorganic Cage-Like Polyhedral Oligomeric Silsesquioxanes between Clay Platelets by Langmuir Schaefer Deposition |
| title_sort |
insertion of iron decorated organic–inorganic cage-like polyhedral oligomeric silsesquioxanes between clay platelets by langmuir schaefer deposition |
| publisher |
MDPI AG |
| series |
Materials |
| issn |
1996-1944 |
| publishDate |
2020-01-01 |
| description |
Tuning the architecture of multilayer nanostructures by exploiting the properties of their constituents is a versatile way to develop multifunctional films. Herein, we report a bottom-up approach for the fabrication of highly ordered hybrid films consisting of dimethyldioctadecylammonium (DODA), iron decorated polyhedral oligomeric silsesquioxanes (POSS), and montmorillonite clay platelets. Clay platelets provided the template where Fe/POSS moieties were grafted by the use of the surfactant. Driven by the iron ions present, DODA adopted a staggered arrangement, which is essential to realize the controllable layer-by-layer growth of the film. The elemental composition of the film was studied by X-ray photoelectron spectroscopy and X-ray reflectivity confirmed the existence of smooth interfaces between the different layers. |
| topic |
langmuir–schaefer polyhedral oligomeric silsesquioxanes layered thin films montmorillonite films |
| url |
https://www.mdpi.com/1996-1944/13/1/216 |
| work_keys_str_mv |
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