Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.

Bibliographic Details
Main Authors: Kruppa Sebastian Volker, Bäppler Florian, Holzer Christof, Dietrich Fabian, Diller Rolf, Klopper Wim, Riehn Christoph
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:EPJ Web of Conferences
Online Access:https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09019.pdf
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spelling doaj-ea56e61c387e4a008f6310d53bd191482021-08-02T13:23:00ZengEDP SciencesEPJ Web of Conferences2100-014X2019-01-012050901910.1051/epjconf/201920509019epjconf_up2019_09019Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand sizeKruppa Sebastian Volker0Bäppler Florian1Holzer Christof2Dietrich Fabian3Diller Rolf4Klopper Wim5Riehn ChristophTU Kaiserslautern, Chemistry Dept.TU Kaiserslautern, Physics Dept.Karlsruhe Institute of Technology, Institute of Physical ChemistryTU Kaiserslautern, Chemistry Dept.TU Kaiserslautern, Physics Dept.Karlsruhe Institute of Technology, Institute of Physical ChemistryUltrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09019.pdf
collection DOAJ
language English
format Article
sources DOAJ
author Kruppa Sebastian Volker
Bäppler Florian
Holzer Christof
Dietrich Fabian
Diller Rolf
Klopper Wim
Riehn Christoph
spellingShingle Kruppa Sebastian Volker
Bäppler Florian
Holzer Christof
Dietrich Fabian
Diller Rolf
Klopper Wim
Riehn Christoph
Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
EPJ Web of Conferences
author_facet Kruppa Sebastian Volker
Bäppler Florian
Holzer Christof
Dietrich Fabian
Diller Rolf
Klopper Wim
Riehn Christoph
author_sort Kruppa Sebastian Volker
title Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
title_short Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
title_full Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
title_fullStr Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
title_full_unstemmed Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
title_sort excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size
publisher EDP Sciences
series EPJ Web of Conferences
issn 2100-014X
publishDate 2019-01-01
description Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.
url https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09019.pdf
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AT bapplerflorian excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
AT holzerchristof excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
AT dietrichfabian excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
AT dillerrolf excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
AT klopperwim excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
AT riehnchristoph excitedstatevibrationalcoherenceinabinuclearmetaladductwavepacketphasedependantmolecularfragmentationundervariationofligandsize
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