Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

Excited state vibrational coherence in a binuclear metal adduct: wave packet phase dependant molecular fragmentation under variation of ligand size

Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.

Bibliographic Details
Main Authors: Kruppa Sebastian Volker, Bäppler Florian, Holzer Christof, Dietrich Fabian, Diller Rolf, Klopper Wim, Riehn Christoph
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:EPJ Web of Conferences
Online Access:https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_09019.pdf
Description
Summary:Ultrafast vibrational coherence with metal-metal stretching mode character is observed for phosphine-bridged d10-d10 complexes of different size, containing the binuclear [Ag2Cl]+ chromophore in an ion trap. Fragmentation pathways are governed by the wave packet's phase.
ISSN:2100-014X

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