8-Iodoquinolinium chloride dihydrate
The title compound, C9H7IN+·Cl−·2H2O, was obtained during the synthesis of 8-iodoquinoline from 8-aminoquinoline using the Sandmeyer reaction. The 8-iodoquinolinium ion is almost planar. Solvent water molecules and chloride ions form a hydrogen-bonded chain along the c ax...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808031528 |
| Summary: | The title compound, C9H7IN+·Cl−·2H2O, was obtained during the synthesis of 8-iodoquinoline from 8-aminoquinoline using the Sandmeyer reaction. The 8-iodoquinolinium ion is almost planar. Solvent water molecules and chloride ions form a hydrogen-bonded chain along the c axis via O—H...Cl links. The 8-iodoquinolinium ions, which are packed along the c axis with cationic aromatic π–π stacking (centroid–centroid distance = 3.624 Å), are linked to the chain via N—H...O hydrogen bonds. |
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| ISSN: | 1600-5368 |