Structural and Optical Characteristics of PVA:C-Dot Composites: Tuning the Absorption of Ultra Violet (UV) Region

• Main Authors: Shujahadeen B. Aziz, Aso Q. Hassan, Sewara J. Mohammed, Wrya O. Karim, M. F. Z. Kadir, H. A. Tajuddin, N. N. M. Y. Chan
• Format: Article
• Language: English
• Published: MDPI AG 2019-02-01
• Series: Nanomaterials
• Subjects: carbon nanodots; hybrid polymer composites; FTIR study; XRD study; optical properties
• Online Access: https://www.mdpi.com/2079-4991/9/2/216

In this work the influence of carbon nano-dots (CNDs) on absorption of ultra violet (UV) spectra in hybrid PVA based composites was studied. The FTIR results reveal the complex formation between PVA and CNDs. The shifting was observed in XRD spectrum of PVA:CNDs composites compared to pure PVA. The Debye-Scherrer formula was used to calculate the crystallite size of CNDs and crystalline phases of pure PVA and PVA:CNDs composites. The FESEM images emphasized the presence and dispersion of C-dots on the surface of the composite samples. From the images, a strong and clear absorption was noticed in the spectra. The strong absorption that appeared peaks at 280 nm and 430 nm can be ascribed to the n-π* and π-π* transitions, respectively. The absorption edge shifted to lower photon energy sides with increasing CNDs. The luminescence behavior of PVA:CNDs composite was confirmed using digital and photo luminescence (PL) measurements. The optical dielectric constant which is related to the density of states was studied and the optical band gap was characterized accurately using optical dielectric loss parameter. The Taucs model was used to determine the type of electronic transition in the samples.