Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether

16-Dehydropregnenolone acetate (16-DPA) (1), an exocyclic α,β-conjugated ketone having a steroidal skeleton, when treated with mercuric(II) acetate in acetic acid furnished a single compound identified as (2). The structure of compound (2) has been elucidated on the basis of spectral data analysis (...

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Main Authors:	Pranab Ghosh, Antara Sarkar, Jayanta Das
Format:	Article
Language:	English
Published:	MDPI AG 2009-09-01
Series:	Molbank
Subjects:	16-DPA mercuric(II) acetate exocyclic α,β-conjugated ketone steroidal skeleton
Online Access:	http://www.mdpi.com/1422-8599/2009/3/M616/

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spelling	doaj-e92ca10b8aea447389954720cefbd2022020-11-24T21:01:13ZengMDPI AGMolbank1422-85992009-09-0120093M61610.3390/M616Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic EtherPranab GhoshAntara SarkarJayanta Das16-Dehydropregnenolone acetate (16-DPA) (1), an exocyclic α,β-conjugated ketone having a steroidal skeleton, when treated with mercuric(II) acetate in acetic acid furnished a single compound identified as (2). The structure of compound (2) has been elucidated on the basis of spectral data analysis (IR, NMR and MS). http://www.mdpi.com/1422-8599/2009/3/M616/16-DPAmercuric(II) acetateexocyclic α,β-conjugated ketonesteroidal skeleton
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Pranab Ghosh Antara Sarkar Jayanta Das
spellingShingle	Pranab Ghosh Antara Sarkar Jayanta Das Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether Molbank 16-DPA mercuric(II) acetate exocyclic α,β-conjugated ketone steroidal skeleton
author_facet	Pranab Ghosh Antara Sarkar Jayanta Das
author_sort	Pranab Ghosh
title	Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether
title_short	Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether
title_full	Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether
title_fullStr	Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether
title_full_unstemmed	Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether
title_sort	mercuric(ii) acetate oxidation of steroidal exocyclic α,β-unsaturated ketone: transformation into a cyclic ether
publisher	MDPI AG
series	Molbank
issn	1422-8599
publishDate	2009-09-01
description	16-Dehydropregnenolone acetate (16-DPA) (1), an exocyclic α,β-conjugated ketone having a steroidal skeleton, when treated with mercuric(II) acetate in acetic acid furnished a single compound identified as (2). The structure of compound (2) has been elucidated on the basis of spectral data analysis (IR, NMR and MS).
topic	16-DPA mercuric(II) acetate exocyclic α,β-conjugated ketone steroidal skeleton
url	http://www.mdpi.com/1422-8599/2009/3/M616/
work_keys_str_mv	AT pranabghosh mercuriciiacetateoxidationofsteroidalexocyclicabunsaturatedketonetransformationintoacyclicether AT antarasarkar mercuriciiacetateoxidationofsteroidalexocyclicabunsaturatedketonetransformationintoacyclicether AT jayantadas mercuriciiacetateoxidationofsteroidalexocyclicabunsaturatedketonetransformationintoacyclicether
_version_	1716778531159015424

Mercuric(II) Acetate Oxidation of Steroidal Exocyclic α,β-Unsaturated Ketone: Transformation into a Cyclic Ether

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