N′-[(1E)-2,5-Dimethoxybenzylidene]pyridine-2-carbohydrazide

N′-[(1E)-2,5-Dimethoxybenzylidene]pyridine-2-carbohydrazide

The molecule of the title compound, C15H15N3O3, is twisted, with the dihedral angle between the pyridyl and benzene rings being 58.34 (6)°. In the crystal, amide-N—H...O(amide) and imine-C—H...O(amide) hydrogen bonds lead to zigzag (glide symmetry) chains extending along the c axis which are joined...

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Bibliographic Details
Main Authors: Mustafa R.Albayati, Joel T. Mague, Mehmet Akkurt, Shaaban K. Mohamed, Sahar M. I. Elgarhy
Format: Article
Language:English
Published: International Union of Crystallography 2018-01-01
Series:IUCrData
Subjects:
crystal structure
pyridine
carbohydrazide
hydrogen bond
π–π stacking
picolinic acid
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314618001281
Description
Summary:The molecule of the title compound, C15H15N3O3, is twisted, with the dihedral angle between the pyridyl and benzene rings being 58.34 (6)°. In the crystal, amide-N—H...O(amide) and imine-C—H...O(amide) hydrogen bonds lead to zigzag (glide symmetry) chains extending along the c axis which are joined into layers parallel to the [100] direction by offset π–π stacking interactions between inversion-related benzene rings [centroid–centroid distance = 3.7468 (7) Å] and by C—H...π(pyridyl) interactions. Pyridyl rings protrude from the surfaces of the layers and partially intercalate with those of adjacent layers.
ISSN:2414-3146

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