Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)

Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)

Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational...

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Main Authors: Varga Filip, Titiš Ján, Rajnák Cyril, Moncoľ Ján, Boča Roman
Format: Article
Language:English
Published: Sciendo 2017-12-01
Series:Nova Biotechnologica et Chimica
Subjects:
Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
Online Access:http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INT
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spelling doaj-e8e60373dc24450d9e97a5e06d6377fa2020-11-25T00:18:21ZengSciendoNova Biotechnologica et Chimica1338-69052017-12-0116213814610.1515/nbec-2017-0019nbec-2017-0019Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)Varga Filip0Titiš Ján1Rajnák Cyril2Moncoľ Ján3Boča Roman4Department of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicInstitute of Inorganic Chemistry, FCHPT, Slovak University of Technology, Bratislava, SK-812 37, Slovak RepublicDepartment of Chemistry, Faculty of Natural Sciences, University of SS. Cyril and Methodius in Trnva, Nám. J. Herdu 2, Trnava, SK-917 01, Slovak RepublicDiamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational methods, and magnetic measurements.http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INTAb initio calculationsCo(III) complexMagnetismNi(II) complexO-ethyl xanthateUV-VIS spectra
collection DOAJ
language English
format Article
sources DOAJ
author Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
spellingShingle Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
Nova Biotechnologica et Chimica
Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
author_facet Varga Filip
Titiš Ján
Rajnák Cyril
Moncoľ Ján
Boča Roman
author_sort Varga Filip
title Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_short Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_full Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_fullStr Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_full_unstemmed Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)
title_sort diamagnetic cobalt(iii)tris(o-ethylxanthate) and nickel(ii)bis(o-ethylxanthate)
publisher Sciendo
series Nova Biotechnologica et Chimica
issn 1338-6905
publishDate 2017-12-01
description Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational methods, and magnetic measurements.
topic Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
url http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INT
work_keys_str_mv AT vargafilip diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT titisjan diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT rajnakcyril diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT moncoljan diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
AT bocaroman diamagneticcobaltiiitrisoethylxanthateandnickeliibisoethylxanthate
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