Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)

Diamagnetic cobalt(III)tris(o-ethylxanthate) and nickel(II)bis(o-ethylxanthate)

Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational...

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Bibliographic Details
Main Authors: Varga Filip, Titiš Ján, Rajnák Cyril, Moncoľ Ján, Boča Roman
Format: Article
Language:English
Published: Sciendo 2017-12-01
Series:Nova Biotechnologica et Chimica
Subjects:
Ab initio calculations
Co(III) complex
Magnetism
Ni(II) complex
O-ethyl xanthate
UV-VIS spectra
Online Access:http://www.degruyter.com/view/j/nbec.2017.16.issue-2/nbec-2017-0019/nbec-2017-0019.xml?format=INT
Description
Summary:Diamagnetic [Co(xanth)3] and [Ni(xanth)2] complexes have been prepared by reaction of Co(II) and Ni(II) salts with potassium O-ethyl xanthate (Kxanth). The isolated Co(III) and Ni(II) complexes have been characterized by single-crystal X-ray crystallography, UV-VIS and IR spectroscopy, computational methods, and magnetic measurements.
ISSN:1338-6905

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