{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate

{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate

In the title compound, [Hg(C42H38N4O2)](PF6)2·2CH3CN, the HgII cation lies on a twofold axis which is also the internal symmetry element of the complete cationic complex. The HgII cation is coordinated by two symmetry-related C(carbene) atoms [Hg—C = 2.058 (9...

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Main Authors: Di-Si Bai, Gui-Ying Dong, Jun-Wen Wang, Yue Guo, Yu Gu
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812005958
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spelling doaj-e89b0ad1828349e692015d81815a5cd72020-11-24T21:32:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m302m30210.1107/S1600536812005958{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvateDi-Si BaiGui-Ying DongJun-Wen WangYue GuoYu GuIn the title compound, [Hg(C42H38N4O2)](PF6)2·2CH3CN, the HgII cation lies on a twofold axis which is also the internal symmetry element of the complete cationic complex. The HgII cation is coordinated by two symmetry-related C(carbene) atoms [Hg—C = 2.058 (9) Å] in a nearly linear geometry, with a C—Hg—C angle of 175.8 (5)°. There are weak intermolecular C—H...F interactions in the crystal packing between an F atom of a hexafluoridophosphate anion and a –CH2– group of the bis-N-heterocyclic carbene ligand.http://scripts.iucr.org/cgi-bin/paper?S1600536812005958
collection DOAJ
language English
format Article
sources DOAJ
author Di-Si Bai
Gui-Ying Dong
Jun-Wen Wang
Yue Guo
Yu Gu
spellingShingle Di-Si Bai
Gui-Ying Dong
Jun-Wen Wang
Yue Guo
Yu Gu
{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
Acta Crystallographica Section E
author_facet Di-Si Bai
Gui-Ying Dong
Jun-Wen Wang
Yue Guo
Yu Gu
author_sort Di-Si Bai
title {3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
title_short {3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
title_full {3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
title_fullStr {3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
title_full_unstemmed {3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
title_sort {3,3′-bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(ii) bis(hexafluoridophosphate) acetonitrile disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description In the title compound, [Hg(C42H38N4O2)](PF6)2·2CH3CN, the HgII cation lies on a twofold axis which is also the internal symmetry element of the complete cationic complex. The HgII cation is coordinated by two symmetry-related C(carbene) atoms [Hg—C = 2.058 (9) Å] in a nearly linear geometry, with a C—Hg—C angle of 175.8 (5)°. There are weak intermolecular C—H...F interactions in the crystal packing between an F atom of a hexafluoridophosphate anion and a –CH2– group of the bis-N-heterocyclic carbene ligand.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812005958
work_keys_str_mv AT disibai 33amp8242bisanthracen9ylmethyl11amp8242ethane12diyldioxybisethane12diylbisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitriledisolvate
AT guiyingdong 33amp8242bisanthracen9ylmethyl11amp8242ethane12diyldioxybisethane12diylbisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitriledisolvate
AT junwenwang 33amp8242bisanthracen9ylmethyl11amp8242ethane12diyldioxybisethane12diylbisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitriledisolvate
AT yueguo 33amp8242bisanthracen9ylmethyl11amp8242ethane12diyldioxybisethane12diylbisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitriledisolvate
AT yugu 33amp8242bisanthracen9ylmethyl11amp8242ethane12diyldioxybisethane12diylbisimidazol2ylidenemercuryiibishexafluoridophosphateacetonitriledisolvate
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